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@ARTICLE{AguilarSanchez:328,
      author       = {Aguilar-Sanchez, R. and Su, G.J. and Homberger, M. and
                      Simon, U. and Wandlowski, Th.},
      title        = {{S}tructure and electrochemical characterization of
                      w-(4'-methyl-biphenyl-4-yl) alkanthiols on {A}u(111)-(1x1)
                      electrodes},
      journal      = {The journal of physical chemistry / C},
      volume       = {111},
      issn         = {1932-7447},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {PreJuSER-328},
      pages        = {17409-17419},
      year         = {2007},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {4-Methyl-4'-(n-mercaptoalkyl)biphenyl
                      (CH3-C6H4-C6H4-(CH2)(n)-SH, n = 1-6, BPn) monolayers
                      self-assembled on Au(111)-(1 x 1) electrode surfaces were
                      studied by scanning tunneling microscopy, cyclic
                      voltammetry, and chronoamperometry. Distinct odd-even
                      effects were found for the adlayer structures, the
                      interfacial adlayer capacitances, as well as for the
                      potentials and charges of reductive and oxidative
                      desorption. The potential of zero charge, E-pzc, of
                      BPn-modified gold electrodes was estimated by a controlled
                      immersion technique in hanging meniscus configuration to
                      E-pzc = -(0.30 +/- 0.05) V, rather independent of the length
                      of the alkyl spacer. The reductive desorption of BP3 and BP4
                      adlayers were quantitatively described by models based on
                      hole nucleation and growth mechanisms, such as the
                      exponential law of one-step hole nucleation (BP3), or hole
                      nucleation according to a.power law (BP3, BP4) in
                      combination with a linear law of growth. No odd-even
                      characteristics were found for the kinetic currents of the
                      Fe(CN)(6)(4-)/Fe(CN)(6)(3-) redox reaction in the presence
                      of BPn's. For the dependence on alkyl chain length, a
                      structure sensitive attenuation parameter beta = (11.5 +/-
                      1.0) nm(-1) was derived, which is interpreted according to a
                      "through-bond" tunneling mechanism.},
      keywords     = {J (WoSType)},
      cin          = {IBN-3 / CNI / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB801 / I:(DE-Juel1)VDB381 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Chemistry, Physical / Nanoscience $\&$ Nanotechnology /
                      Materials Science, Multidisciplinary},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000251024500037},
      doi          = {10.1021/jp0744634},
      url          = {https://juser.fz-juelich.de/record/328},
}