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000032828 084__ $$2WoS$$aBiochemistry & Molecular Biology
000032828 084__ $$2WoS$$aBiophysics
000032828 1001_ $$0P:(DE-Juel1)128805$$aCsiszar, A.$$b0$$uFZJ
000032828 245__ $$aEffect of 2,4-dichlorophenol on DPPC/water liposomes studied by X-ray and freeze-fracture electron microscopy
000032828 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2003
000032828 300__ $$a155 - 166
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000032828 440_0 $$010461$$aChemistry and Physics of Lipids$$v126$$x0009-3084
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000032828 520__ $$aThe effect of 2,4-dichlorophenol (DCP) was studied on the fully hydrated 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC)-water liposomes. The structure and the thermotropic phase behaviour of the liposomes was examined in the presence of DCP (DCP/DPPC molar ratio, varied from 2 x 10(-2) up to 1) using small- and wide-angle X-ray scattering (SAXS, WAXS) and freeze-fracture electron microscopy. The structural behaviour of the DPPC/DCP/water system was strongly dependent on the concentration of the DCR In the pretransition range the DCP molecules (at 2 x 10(-2) DCP/DPPC molar ratio) induced the interdigitated phase beside the parent (gel and rippled gel) phases, locally which can be form at higher DCP concentration. When the DCP/DPPC molar ratio was increased the pretransition disappeared and the main transition was shifted to lower temperatures. In the molar ratio range from 2 x 10(-1) up to 5 x 10(-1), a coexistence of different phases was observed in the wide temperature range from 20 up to 40 degreesC. With a further increase of the DCP/DPPC molar ratio (6 x 10(-1) to 1) only the interdigitated gel phase occurred below 25 degreesC. A schematic phase diagram of DPPC/DCP/water system was constructed to summarise the results. (C) 2003 Elsevier Ireland Ltd. All rights reserved.
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000032828 65320 $$2Author$$aDPPC liposomes
000032828 65320 $$2Author$$a2,4-dichlorophenol
000032828 65320 $$2Author$$aSAXS
000032828 65320 $$2Author$$aWAXS
000032828 65320 $$2Author$$afreeze-fracture
000032828 65320 $$2Author$$aphase diagram
000032828 7001_ $$0P:(DE-Juel1)129484$$aKlumpp, E.$$b1$$uFZJ
000032828 7001_ $$0P:(DE-HGF)0$$aBota, A.$$b2
000032828 7001_ $$0P:(DE-HGF)0$$aSzegedi, K.$$b3
000032828 773__ $$0PERI:(DE-600)1496839-3$$a10.1016/j.chemphyslip.2003.08.005$$gVol. 126, p. 155 - 166$$p155 - 166$$q126<155 - 166$$tChemistry and physics of lipids$$v126$$x0009-3084$$y2003
000032828 8567_ $$uhttp://dx.doi.org/10.1016/j.chemphyslip.2003.08.005
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