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@ARTICLE{Klumpp:32830,
author = {Klumpp, E. and Contreras-Ortega, C. and Klahre, P. and
Tino, F. J. and Yapar, S. and Portillo, C. and Stegen, F.
and Queirolo, F. and Schwuger, M. J.},
title = {{S}orption of 2,4-dichlorophenol on modified hydrotalcites},
journal = {Colloids and surfaces / A},
volume = {230},
issn = {0927-7757},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PreJuSER-32830},
pages = {111 - 116},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {The adsorption of anionic surfactants (sodium dodecyl
sulfate (SDS) and sodium bis[2-ethylhexil]sulfosuccinate
(AOT)) on hydrotalcite (HT) and the adsorption of
2,4-dichlorophenol (DCP) on HT and its modified forms from
aqueous solutions was studied. The modification was carried
out by calcinations (heat treatment) and hydrophobization
using different anionic surfactants. The anionic surfactant
isotherms were of the H-type. It was assumed that first the
ion exchange mechanism takes place until approximately the
anion exchange capacity of HT is reached and hereafter, the
hydrophobic mechanism occurs forming surfactant bilayers.
While the DCP adsorption was very poor on HT, significant
uptake of DCP took place on calcined HT which was attributed
to the simultaneously occurring rehydration and adsorption
during the reconstruction of the layered structure. On
anionic surfactant-HT complexes ("organo-hydrotalcites") DCP
was considerably adsolubilized in the anionic surfactant
layers intercalated in HT. The AOT-HT complex appeared the
more effective adsorbents for DCP. (C) 2003 Elsevier B.V.
All rights reserved.},
keywords = {J (WoSType)},
cin = {ICG-IV},
ddc = {540},
cid = {I:(DE-Juel1)VDB50},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Chemistry, Physical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000188059700012},
doi = {10.1016/j.colsurfa.2003.09.018},
url = {https://juser.fz-juelich.de/record/32830},
}