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@ARTICLE{Wirtz:32923,
author = {Wirtz, L. and Burgdorfer, J. and Dallos, M. and Müller, T.
and Lischka, H.},
title = {{P}otential-energy surfaces for charge exchange between
singly charged ions and a {L}i{F} surface},
journal = {Physical review / A},
volume = {68},
number = {3},
issn = {1050-2947},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-32923},
pages = {032902},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {We analyze the adiabatic potential-energy surfaces relevant
for neutralization of singly charged ions in slow vertical
incidence onto a lithium fluoride surface. The surface is
represented by a cluster of varying size augmented by point
charges of alternating sign in order to include the proper
Madelung potential of the ionic crystal. Our calculation
proceeds on the multiconfiguration self-consistent-field and
multireference configuration-interaction levels.
Size-consistency corrections based on the Davidson
correction and multireference averaged quadratic coupled
cluster methods are included as well. We emphasize the
importance of a proper treatment of electron correlation
signifying the polarization of the surrounding cluster
environment in ab initio calculations of charge transfer at
surfaces. From the topology of the surfaces, in particular
the existence or absence of avoided crossings (or, more
generally, conical intersections), qualitative predictions
for the neutralization process can be made. The comparative
analysis of potential curves for H+, C+, S+, and Ne+
projectiles provides an explanation for the recently
observed threshold behavior for potential sputtering.},
keywords = {J (WoSType)},
cin = {ZAM},
ddc = {530},
cid = {I:(DE-Juel1)VDB62},
pnm = {Betrieb und Weiterentwicklung des Höchstleistungsrechners},
pid = {G:(DE-Juel1)FUEK254},
shelfmark = {Optics / Physics, Atomic, Molecular $\&$ Chemical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000185716700073},
doi = {10.1103/PhysRevA.68.032902},
url = {https://juser.fz-juelich.de/record/32923},
}