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@ARTICLE{Weibel:330,
      author       = {Weibel, T. and Blaszczyk, A. and von Hänisch, C. and
                      Mayor, M. and Pobelov, I. and Wandlowski, Th. and Chen, F.
                      and Tao, N.},
      title        = {{R}edox-active catechol-functionalized molecular rods:
                      {S}uitable protection groups and single-molecule transport
                      investigations},
      journal      = {European journal of organic chemistry},
      issn         = {1434-193X},
      address      = {Weinheim},
      publisher    = {Wiley-VCH Verl.},
      reportid     = {PreJuSER-330},
      pages        = {136 - 149},
      year         = {2008},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The synthesis of molecular rod 1 comprising a central
                      redoxactive unit and two terminal acetyl-protected sulfur
                      groups is reported. Various protecting groups for the
                      catechol moiety were investigated and protected precursors
                      14-18 were synthesized. In particular, ethyl orthoformate 17
                      can be easily and selectively deprotected in mild acidic
                      conditions ruling out the need for a strong Lewis acid like
                      boron tribromide. The redox activity of I was confirmed by
                      cyclic voltammetric investigations. Gold-molecule-gold
                      junctions were formed with the dimethyl-protected rod 18.
                      Single-molecule transport investigations using this
                      molecular rod revealed a set of three single-junction
                      conductance values varying over two orders of magnitude.
                      ((c) Wiley-VCH Verlag GmbH $\&$ Co. KGaA, 69451 Weinheim,
                      Germany, 2008).},
      keywords     = {J (WoSType)},
      cin          = {IBN-3 / CNI / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB801 / I:(DE-Juel1)VDB381 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Chemistry, Organic},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000252681800013},
      doi          = {10.1002/ejoc.200700810},
      url          = {https://juser.fz-juelich.de/record/330},
}