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@ARTICLE{Klemp:33399,
author = {Klemp, D. and Mannschreck, K. and Pätz, H.-W. and Habram,
M. and Matuska, P. and Slemr, E. C.},
title = {{D}etermination of anthropogenic emission ratios in the
{A}ugsburg area from concentration ratios : results from
long-term measurements},
journal = {Atmospheric environment},
volume = {36},
issn = {1352-2310},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PreJuSER-33399},
pages = {61 - 80},
year = {2002},
note = {Record converted from VDB: 12.11.2012},
abstract = {As part of a joint coordinated effort of several
institutions to experimentally assess the uncertainty of
highly resolved CO, NOx and VOC emission inventories, this
paper presents the emission ratios derived from the
concentrations measured at a receptor site. For this
purpose, representative data sets on concentrations in the
plume of Augsburg were obtained during two 4-week long
campaigns in March and October 1998. Characteristic emission
ratios and their experimental uncertainties have been
determined for pure non-methane-hydrocarbons
(NMHC/NOx-ratios, NMHC/CO-ratios) and for formaldehyde
(HCHO/NOx-ratios, HCHO/CO-ratios) by means of correlation
analyses. Special emphasis is also placed on the detailed
hydrocarbon composition profile, the mean diurnal behavior
of the emissions and the characterization of differences
between weekdays and weekends as well as between seasons.The
emission ratios at the receptor ground site were generally
found to be in reasonable agreement with the emission ratios
determined from the concurrent measurements onboard an
aircraft. This agreement is remarkable in view of the
difference between the aircraft and ground measurements.
Circling around the city as is performed by air-borne
measurements yields a good spatial average of the emissions
released from the city, but the small number of measurement
days limits their statistical representativity. Receptor
ground-based measurements downwind of the city, on the other
hand, cover many days during the long-term investigation,
but may not be representative for the emissions of the whole
city. Thus, the observed agreement between ground-based and
air-borne studies strongly supports the assumption of
spatial representativity for the long-term data
set.Comparisons of mean hydrocarbon emission profiles
measured in Augsburg with those measured over Berlin, in
streets of Berlin and Munich as well as with the mean German
urban hydrocarbon composition show that Augsburg is a
typical German city with respect to its NMHC emission
profiles and that these profiles, at least for the measured
NMHC compounds, are dominated by traffic related NMHC
emissions. (C) 2002 Elsevier Science Ltd. All rights
reserved.},
keywords = {J (WoSType)},
cin = {ICG-II},
ddc = {550},
cid = {I:(DE-Juel1)VDB48},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Environmental Sciences / Meteorology $\&$ Atmospheric
Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000177154100006},
url = {https://juser.fz-juelich.de/record/33399},
}