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@ARTICLE{Frielinghaus:34172,
author = {Frielinghaus, H. and Hermsdorf, N. and Sigel, R. and
Almdal, K. and Mortensen, K. and Hamley, I. W. and Messé,
L. and Corvazier, M. F. and Ryan, A. J. and van Dusschoten,
D. and Wilhelm, M. and Floudas, G. and Fytas, G.},
title = {{B}lends of {AB}/{BC} diblock copolymers with a large
interaction parameter {C}hi},
journal = {Macromolecules},
volume = {34},
issn = {0024-9297},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PreJuSER-34172},
pages = {4907 - 4916},
year = {2001},
note = {Record converted from VDB: 12.11.2012},
abstract = {Blends of poly(styrene)-b-poly(isoprene) (PS-PI) and poly(
isoprene)-b-poly(ethylene oxide) (PI-PEO) were investigated
by small-angle X-ray scattering, photon correlation
spectroscopy, light microscopy, and rheology. Blends were
prepared in which both diblocks had the same PI composition,
f, and were investigated as a function of blend composition,
Phi. We generally found a disordered one-phase region at
high temperatures and two macrophase-separated, ordered
phases at low temperatures. At low temperatures the only
appreciable miscibility was found for f = 0.7 in the
PI-PEO-rich phase. At intermediate temperatures we generally
observed macrophase separation before microphase separation
upon cooling. The macrophase separation boundary compared to
the microphase boundary is lowered upon increasing f. For f
= 0.6 and 0.7 we observe an adjustment of the d spacing of
the macrophase-separated, ordered phases. The general trend
of the phase behavior is described by a theory using the
random phase approximation.},
keywords = {J (WoSType)},
cin = {IFF-NST},
ddc = {540},
cid = {I:(DE-Juel1)VDB34},
pnm = {Polymere, Membranen und komplexe Flüssigkeiten},
pid = {G:(DE-Juel1)FUEK53},
shelfmark = {Polymer Science},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000169564100036},
doi = {10.1021/ma010233q},
url = {https://juser.fz-juelich.de/record/34172},
}