001     34172
005     20240619091749.0
024 7 _ |a 10.1021/ma010233q
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024 7 _ |a 2128/1296
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037 _ _ |a PreJuSER-34172
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Polymer Science
100 1 _ |a Frielinghaus, H.
|0 P:(DE-Juel1)VDB4228
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|u FZJ
245 _ _ |a Blends of AB/BC diblock copolymers with a large interaction parameter Chi
260 _ _ |a Washington, DC
|b Soc.
|c 2001
300 _ _ |a 4907 - 4916
336 7 _ |a Journal Article
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440 _ 0 |a Macromolecules
|x 0024-9297
|0 4142
|v 34
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Blends of poly(styrene)-b-poly(isoprene) (PS-PI) and poly( isoprene)-b-poly(ethylene oxide) (PI-PEO) were investigated by small-angle X-ray scattering, photon correlation spectroscopy, light microscopy, and rheology. Blends were prepared in which both diblocks had the same PI composition, f, and were investigated as a function of blend composition, Phi. We generally found a disordered one-phase region at high temperatures and two macrophase-separated, ordered phases at low temperatures. At low temperatures the only appreciable miscibility was found for f = 0.7 in the PI-PEO-rich phase. At intermediate temperatures we generally observed macrophase separation before microphase separation upon cooling. The macrophase separation boundary compared to the microphase boundary is lowered upon increasing f. For f = 0.6 and 0.7 we observe an adjustment of the d spacing of the macrophase-separated, ordered phases. The general trend of the phase behavior is described by a theory using the random phase approximation.
536 _ _ |a Polymere, Membranen und komplexe Flüssigkeiten
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700 1 _ |a Hermsdorf, N.
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700 1 _ |a Sigel, R.
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700 1 _ |a Almdal, K.
|0 P:(DE-HGF)0
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700 1 _ |a Mortensen, K.
|0 P:(DE-HGF)0
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700 1 _ |a Hamley, I. W.
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700 1 _ |a Messé, L.
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700 1 _ |a Corvazier, M. F.
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700 1 _ |a Ryan, A. J.
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700 1 _ |a van Dusschoten, D.
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700 1 _ |a Wilhelm, M.
|0 P:(DE-HGF)0
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700 1 _ |a Floudas, G.
|0 P:(DE-HGF)0
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700 1 _ |a Fytas, G.
|0 P:(DE-HGF)0
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773 _ _ |a 10.1021/ma010233q
|g Vol. 34, p. 4907 - 4916
|p 4907 - 4916
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|0 PERI:(DE-600)1491942-4
|t Macromolecules
|v 34
|y 2001
|x 0024-9297
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913 1 _ |k 23.30.0
|v Polymere, Membranen und komplexe Flüssigkeiten
|l Festkörperforschung
|b Struktur der Materie und Materialforschung
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914 1 _ |y 2001
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