001     34174
005     20240619091749.0
024 7 _ |2 DOI
|a 10.1088/0953-8984/13/41/302
024 7 _ |2 WOS
|a WOS:000172033800006
037 _ _ |a PreJuSER-34174
041 _ _ |a eng
082 _ _ |a 530
084 _ _ |2 WoS
|a Physics, Condensed Matter
100 1 _ |a Gompper, G.
|0 P:(DE-Juel1)130665
|b 0
|u FZJ
245 _ _ |a Amphiphilic block copolymers in oil-water-surfactant mixtures : efficiency boosting, structure, phase behavior and mechanism
260 _ _ |a Bristol
|b IOP Publ.
|c 2001
300 _ _ |a 9055 - 9074
336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a article
|2 DRIVER
440 _ 0 |a Journal of Physics: Condensed Matter
|x 0953-8984
|0 3703
|v 13
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The effect of amphiphilic block copolymers on the phase behaviour and structure of ternary microemulsions in water, oil and non-ionic surfactant mixtures is reviewed. Recent experiments have revealed that the addition of small amounts of polyethylenepropylene-polyethyleneoxide block copolymer to the ternary systems leads to a dramatic increase in the volumes of oil and water solubilized into a bicontinuous microemulsion for a given surfactant volume fraction. While phase diagrams directly show the power of the amphiphilic block copolymers as efficiency boosters, the theoretical analysis in terms of bending energy discloses the mechanism for the efficiency boosting as due to the variation of the surfactant film curvature elasticity by tethered polymers in the form of mushrooms at the interface. Neutron scattering experiments employing a high-precision two-dimensional contrast variation technique confirm this picture and demonstrate that the polymer molecules uniformly decorate the surfactant film.
536 _ _ |a Polymere, Membranen und komplexe Flüssigkeiten
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700 1 _ |a Richter, D.
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700 1 _ |a Strey, R.
|0 P:(DE-HGF)0
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773 _ _ |a 10.1088/0953-8984/13/41/302
|g Vol. 13, p. 9055 - 9074
|p 9055 - 9074
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|0 PERI:(DE-600)1472968-4
|t Journal of physics / Condensed matter
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|y 2001
|x 0953-8984
909 C O |o oai:juser.fz-juelich.de:34174
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913 1 _ |k 23.30.0
|v Polymere, Membranen und komplexe Flüssigkeiten
|l Festkörperforschung
|b Struktur der Materie und Materialforschung
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|x 0
914 1 _ |y 2001
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |k IFF-NST
|l Neutronenstreuung
|d 31.12.2003
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|0 I:(DE-Juel1)VDB34
|x 0
920 1 _ |k IFF-TH-II
|l Theorie II
|d 31.12.2006
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