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@ARTICLE{Platt:34288,
      author       = {Platt, U. and Alicke, B. and Dubois, R. and Geyer, A. and
                      Hofzumahaus, A. and Holland, F. and Martinez, M. and
                      Mihelcic, D. and Klüpfel, T. and Lohrmann, B. and Pätz,
                      H.-W. and Perner, C. R. and Rohrer, F. and Schäfer, J. and
                      Stutz, J.},
      title        = {{F}ree radicals and fast photochemistry during {BERLIOZ}},
      journal      = {Journal of atmospheric chemistry},
      volume       = {42},
      issn         = {0167-7764},
      address      = {Dordrecht [u.a.]},
      publisher    = {Springer Science + Business Media B.V},
      reportid     = {PreJuSER-34288},
      pages        = {359 - 394},
      year         = {2002},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The free radicals OH, HO2, RO2, and NO3 are known to be the
                      driving force for most chemical processes in the atmosphere.
                      Since the low concentration of the above radicals makes
                      measurements particularly difficult, only relatively few
                      direct measurements of free radical concentrations have been
                      reported to date. We present a comprehensive set of
                      simultaneous radical measurements performed by Laser Induced
                      Fluorescence (LIF), Matrix Isolation - Electron spin
                      Resonance (MI-ESR), Peroxy Radical Chemical Amplification
                      (PERCA), and Differential Optical Absorption Spectroscopy
                      (DOAS) during the BERLIner OZonexperiment (BERLIOZ) during
                      July and August of 1998 near Berlin, Germany. Most of the
                      above radical species were measured by more than one
                      technique and an intercomparison gave good agreement. This
                      data set offered the possibility to study and quantify the
                      role of each radical at a rural, semi-polluted site in the
                      continental boundary layer and to investigate
                      interconnections and dependencies among these free radicals.
                      In general (box) modelled diurnal profiles of the different
                      radicals reproduced the measurements quite well, however
                      measured absolute levels are frequently lower than model
                      predictions. These discrepancies point to disturbing
                      deficiencies in our understanding of the chemical system in
                      urban air masses. In addition considerable night-time peroxy
                      radical production related to VOC reactions with NO3 and O-3
                      could be quantified.},
      keywords     = {J (WoSType)},
      cin          = {ICG-II},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB48},
      pnm          = {Chemie und Dynamik der Geo-Biosphäre},
      pid          = {G:(DE-Juel1)FUEK257},
      shelfmark    = {Environmental Sciences / Meteorology $\&$ Atmospheric
                      Sciences},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000175947400016},
      doi          = {10.1023/A:1015707531660},
      url          = {https://juser.fz-juelich.de/record/34288},
}