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@ARTICLE{Rckmann:34882,
author = {Röckmann, T. and Grooß, J. U. and Müller, R.},
title = {{T}he impact of anthropogenic chlorine emissions,
stratospheric ozone change and chemical feedbacks on
stratospheric water},
journal = {Atmospheric chemistry and physics},
volume = {4},
issn = {1680-7316},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {PreJuSER-34882},
pages = {693 -699},
year = {2004},
note = {Record converted from VDB: 12.11.2012},
abstract = {Mixing ratios of water (H2O) in the stratosphere appear to
increase due to increased input of H2O and methane from the
troposphere and due to intensified oxidation of CH4 in the
stratosphere, but many of the underlying mechanisms are not
yet understood. Here we identify and quantify three chemical
mechanisms which must have led to more efficient oxidation
of CH4 in the stratosphere over the past several decades: 1)
The increase in stratospheric chlorine levels due to
anthropogenic CFC emissions, 2) the thinning of the
stratospheric ozone column and 3) enhanced OH levels in the
stratosphere due to increasing H2O levels themselves. In
combination with the increase in tropospheric CH4 mixing
ratios and with solar cycle related variations of upper
stratospheric ozone, these effects can explain about $50\%$
of the additional conversion of CH4 to H2O as observed
throughout the stratosphere. The relative contributions from
the individual processes have varied over the past decades.},
keywords = {J (WoSType)},
cin = {ICG-I},
ddc = {550},
cid = {I:(DE-Juel1)VDB47},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Meteorology $\&$ Atmospheric Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000221380000003},
url = {https://juser.fz-juelich.de/record/34882},
}