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100 1 _ |a Jablonowski, N. D.
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245 _ _ |a Bioaccessibility of environmentally Aged 14C-Atrazine Residues in an Agriculturally Used Soil and its Particle-Size Aggregates
260 _ _ |c 2008
|a Columbus, Ohio
|b American Chemical Society
300 _ _ |a 5904 - 5910
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440 _ 0 |a Environmental Science and Technology
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520 _ _ |a After 22 years of aging under natural conditions in an outdoor lysimeter the bioaccessibility of C-14-labeled atrazine soil residues to bacteria was tested. Entire soil samples as well as sand-sized, silt-sized, and clay-sized aggregates (> 20, 20-2, and < 2 mu m aggregate size, respectively) were investigated under slurried conditions. The mineralization of residual radioactivity in the outdoor lysimeter soil reached up to 4.5% of the total C-14-activity after 16 days, inoculated with Pseudomonas sp. strain ADP. The control samples without inoculated bacteria showed a mineralization maximum of only about 1% after 44 days of incubation. Mineralization increased in the clay-sized aggregates up to 6.2% of the total residual 14C-activity within 23 days. With decreasing soil aggregate sizes, residual C-14-activity increased per unit of weight, but only minor differences of the mineralization in the soil and soil size aggregates using mineral-media for incubation was observed. Using additional Na-citrate in the incubation,the extent of mineralization increased to 6.7% in soil after 23 days following incubation with Pseudomonas sp. strain ADP. These results show that long-term aged IT-atrazine residues are still partly accessible to the atrazine degrading microorganism Pseudomonas sp. strain ADP.
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700 1 _ |a Modler, J.
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700 1 _ |a Schäffer, A.
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700 1 _ |a Burauel, P.
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