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000003805 0247_ $$2pmid$$apmid:19197965
000003805 0247_ $$2DOI$$a10.1002/smll.200800802
000003805 0247_ $$2WOS$$aWOS:000264327500013
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000003805 041__ $$aeng
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000003805 084__ $$2WoS$$aChemistry, Multidisciplinary
000003805 084__ $$2WoS$$aChemistry, Physical
000003805 084__ $$2WoS$$aNanoscience & Nanotechnology
000003805 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000003805 084__ $$2WoS$$aPhysics, Applied
000003805 084__ $$2WoS$$aPhysics, Condensed Matter
000003805 1001_ $$0P:(DE-Juel1)VDB42769$$aMüller-Meskamp, L.$$b0$$uFZJ
000003805 245__ $$aField Emission Resonances at Tip/alpha, omega-Mercaptoalkyl-ferrocene/Au Interfaces Studied by STM
000003805 260__ $$aWeinheim$$bWiley-VCH Verl.$$c2009
000003805 300__ $$a496 - 502
000003805 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
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000003805 3367_ $$2DRIVER$$aarticle
000003805 440_0 $$016041$$aSmall$$v5$$x1613-6810$$y4
000003805 500__ $$aThe authors thank Christina Lennartz, Peter Kowalzik, Hans Haselier, Holger John, Birgit Hahn, and Jutto Kiesgen for their support and the Institute for Functional Materials for Information Technology (IFMIT) for funding.
000003805 520__ $$aThe electrical properties of alpha,omega-mercaptoalkyl ferrocenes with different alkyl chain lengths embedded in a self-assembled host matrix of alkanethiols on Au(111) are studied by scanning tunneling microscopy and spectroscopy. Based on current-distance spectroscopy, as well as on the evaluation of Fowler-Nordheim tunneling current oscillations, the apparent barrier height of ferrocene is determined independently by two methods. The electronic coupling of the ferrocene moiety to the Au(111) substrate is shown to depend on the length of the alkane-spacer chain. In a double tunnel junction model our experimental findings are explained, addressing the role of the different molecular moieties of the mercaptoalkyl ferrocenes.
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000003805 650_2 $$2MeSH$$aFerrous Compounds: chemistry
000003805 650_2 $$2MeSH$$aGold: chemistry
000003805 650_2 $$2MeSH$$aMicroscopy, Scanning Tunneling: methods
000003805 650_7 $$00$$2NLM Chemicals$$aFerrous Compounds
000003805 650_7 $$0102-54-5$$2NLM Chemicals$$aferrocene
000003805 650_7 $$07440-57-5$$2NLM Chemicals$$aGold
000003805 650_7 $$2WoSType$$aJ
000003805 65320 $$2Author$$acharge transfer
000003805 65320 $$2Author$$aferrocene
000003805 65320 $$2Author$$afield-emission resonance
000003805 65320 $$2Author$$ascanning tunneling microscopy
000003805 65320 $$2Author$$aself-assembled monolayers
000003805 7001_ $$0P:(DE-Juel1)130751$$aKarthäuser, S.$$b1$$uFZJ
000003805 7001_ $$0P:(DE-HGF)0$$aZandvliet, H.J.W.$$b2
000003805 7001_ $$0P:(DE-Juel1)VDB58025$$aHomberger, M.$$b3$$uFZJ
000003805 7001_ $$0P:(DE-Juel1)VDB50065$$aSimon, U.$$b4$$uFZJ
000003805 7001_ $$0P:(DE-Juel1)131022$$aWaser, R.$$b5$$uFZJ
000003805 773__ $$0PERI:(DE-600)2168935-0$$a10.1002/smll.200800802$$gVol. 5, p. 496 - 502$$p496 - 502$$q5<496 - 502$$tSmall$$v5$$x1613-6810$$y2009
000003805 8567_ $$uhttp://dx.doi.org/10.1002/smll.200800802
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000003805 9141_ $$y2009
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000003805 9201_ $$0I:(DE-Juel1)VDB786$$d31.12.2010$$gIFF$$kIFF-6$$lElektronische Materialien$$x0
000003805 9201_ $$0I:(DE-82)080009_20140620$$gJARA$$kJARA-FIT$$lJülich-Aachen Research Alliance - Fundamentals of Future Information Technology$$x1
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