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@ARTICLE{Sougrati:388843,
      author       = {Sougrati, Moulay T. and Darwiche, Ali and Liu, Xiaohiu and
                      Mahmoud, Abdelfattah and Jouen, Samuel and Monconduit, Laure
                      and Dronskowski, Richard and Stievano, Lorenzo and Hermann,
                      Raphael},
      title        = {{T}ransition-{M}etal {C}arbodiimides as {M}olecular
                      {N}egative {E}lectrode {M}aterials for {L}ithium- and
                      {S}odium-{I}on {B}atteries with {E}xcellent {C}ycling
                      {P}roperties},
      journal      = {Angewandte Chemie / International edition},
      volume       = {55},
      number       = {16},
      issn         = {1433-7851},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2016-02076},
      pages        = {5090–5095},
      year         = {2016},
      abstract     = {We report evidence for the electrochemical activity of
                      transition-metal carbodiimides versus lithium and sodium. In
                      particular, iron carbodiimide, FeNCN, can be efficiently
                      used as negative electrode material for alkali-metal-ion
                      batteries, similar to its oxide analogue FeO. Based on 57Fe
                      Mössbauer and infrared spectroscopy (IR) data, the
                      electrochemical reaction mechanism can be explained by the
                      reversible transformation of the Fe−NCN into Li/Na−NCN
                      bonds during discharge and charge. These new electrode
                      materials exhibit higher capacity compared to
                      well-established negative electrode references such as
                      graphite or hard carbon. Contrary to its oxide analogue,
                      iron carbodiimide does not require heavy treatments (such as
                      nanoscale tailoring, sophisticated textures, or coating) to
                      obtain long cycle life with current density as high as
                      9 A g−1 for hundreds of charge–discharge cycles.
                      Similar to the iron compound, several other transition-metal
                      carbodiimides Mx(NCN)y with M=Mn, Cr, Zn can cycle
                      successfully versus lithium and sodium. Their
                      electrochemical activity and performance open the way to the
                      design of a novel family of anode materials.},
      cin          = {JCNS-2 / PGI-4 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {144 - Controlling Collective States (POF3-144) / 524 -
                      Controlling Collective States (POF3-524) / 6212 - Quantum
                      Condensed Matter: Magnetism, Superconductivity (POF3-621) /
                      6213 - Materials and Processes for Energy and Transport
                      Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron
                      Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 /
                      G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6213 /
                      G:(DE-HGF)POF3-6G4},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000374496100041},
      pubmed       = {pmid:26989882},
      doi          = {10.1002/anie.201600098},
      url          = {https://juser.fz-juelich.de/record/388843},
}