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@ARTICLE{Meilinger:39932,
author = {Meilinger, S. K. and Tsias, A. H. and Dreiling, V. and
Kuhn, M. and Feigl, C. and Schlager, H. and Curtius, J. and
Sierau, B. and Arnold, F. and Zöger, M. and Schiller, C.
and Peter, T.},
title = {{HNO}3 partitioning in cirrus clouds},
journal = {Geophysical research letters},
volume = {26},
issn = {0094-8276},
address = {Washington, DC},
publisher = {American Geophysical Union},
reportid = {PreJuSER-39932},
pages = {2207 - 2210},
year = {1999},
note = {Record converted from VDB: 12.11.2012},
abstract = {During the 1997 POLSTAR-1 winter campaign in northern
Sweden a flight was performed across a cold trough of air
(similar or equal to 196 K) in the tropopause region.
Measurements of total water vapour, nitric acid, particles
and reactive nitrogen (NOy) were taken. The particle
measurements indicate that about $3\%$ of the particles in
the moist tropospheric air were ice particles. Forward and
backward facing NOy inlets were used simultaneously to
determine condensed phase HNO3. The combined NOy and
particle measurements reveal that less than $1\%$ of a
monolayer of NOy could have resided on the ice particles.
This casts doubt on the hypothesis that sedimenting cirrus
particles generally lead to a strong downward flux of NOy.
In addition to the NOy measurements, independent HNO3
measurements were used to determine total HNO3. Although
quantitative uncertainties do not allow to completely rule
out that the NOy uptake on ice was limited by total HNO3,
the combined NOy and KNO3 data suggest that there was low
uptake of NOy on ice despite abundant HNO3 in the gas phase.
Model studies indicate, that the most likely explanation of
the measured nitric acid partitioning is given by HNO3 in
ternary solution droplets coexisting with almost HNO3 free
ice in the same air mass.},
keywords = {J (WoSType)},
cin = {ICG-1},
ddc = {550},
cid = {I:(DE-Juel1)VDB169},
pnm = {Stratosphärische Chemie},
pid = {G:(DE-Juel1)FUEK71},
shelfmark = {Geosciences, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000081527100044},
doi = {10.1029/1999GL900423},
url = {https://juser.fz-juelich.de/record/39932},
}