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000040222 084__ $$2WoS$$aMeteorology & Atmospheric Sciences
000040222 084__ $$2WoS$$aWater Resources
000040222 1001_ $$0P:(DE-HGF)0$$aLeistra, M.$$b0
000040222 245__ $$aComputations on the Volatilisation of the Fungicide Fenpropimorph from Plants in a Wind Tunnel
000040222 260__ $$aDordrecht [u.a.]$$bSpringer Science + Business Media B.V$$c2004
000040222 300__ $$a133 - 148
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000040222 520__ $$aVolatilisation of pesticides from plants is one of the main pathways for their emission to the environment. A simplified computation model was set up to simulate this volatilisation, including penetration into plants and photochemical transformation as competing processes. Previous wind tunnel experiments using plants sprayed with C-14-labelled fenpropimorph were simulated using the model. Volatilisation could be simulated by diffusion through a laminar air-boundary layer, with a thickness in the range of 0.5-1.0 mm. Rate coefficients of 1.7-4.8 d(-1) had to be used to simulate the penetration of fenpropimorph into different plant species. The rate of phototransformation was lowest when the incoming air stream was filtered through activated carbon, thus minimising the formation of hydroxyl radicals by sunlight. The simulations enabled us to estimate model parameters that could neither be derived from laboratory studies nor could be obtained with pesticide (non-labelled) in the field.
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000040222 65320 $$2Author$$aair
000040222 65320 $$2Author$$adiffusion
000040222 65320 $$2Author$$aleaves
000040222 65320 $$2Author$$amicro-ecosystem
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000040222 65320 $$2Author$$apesticide
000040222 65320 $$2Author$$aphotodegradation
000040222 65320 $$2Author$$atransformation
000040222 65320 $$2Author$$auptake
000040222 65320 $$2Author$$avapour
000040222 7001_ $$0P:(DE-Juel1)VDB1807$$aWolters, A.$$b1$$uFZJ
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