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000040430 084__ $$2WoS$$aChemistry, Analytical
000040430 084__ $$2WoS$$aElectrochemistry
000040430 1001_ $$0P:(DE-Juel1)VDB5443$$aWandlowski, T.$$b0$$uFZJ
000040430 245__ $$aAdsorption of bromide at the Ag(100) electrode surface
000040430 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2001
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000040430 440_0 $$03261$$aJournal of Electroanalytical Chemistry$$v500$$x0022-0728
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000040430 520__ $$aThe adsorption and phase formation of bromide on Ag(100) has been studied by chronocoulometry and surface X-ray scattering (SXS). With increasing electrode potential, bromide undergoes a phase transition from a lattice gas to an ordered c(2 x 2) structure (theta = 0.5). The degree of lateral disorder was estimated by comparing the SXS- and the electrochemical measurements. Based on chronocoulometric experiments, a thermodynamic analysis of charge density data was performed to describe the bromide adsorption at the Ag(100) electrode. The Gibbs surfaces excess, electrosorption valencies, Esin-Markov coefficients, and the Gibbs energy of adsorption, lateral interaction energies as well as surface dipole moments have been estimated. The experimental theta versus E- isotherms are modeled employing (i) a quasi-chemical approximation as well as (ii) the results of a recent Monte Carlo simulation. An attempt is made to discuss the structure data and thermodynamic quantities of bromide adsorption on Ag(100) on the basis of the Grahame-Parsons model of the Helmholtz layer. (C) 2001 Elsevier Science B.V. All rights reserved.
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000040430 65320 $$2Author$$abromide adsorption
000040430 65320 $$2Author$$aAg(100) electrodes
000040430 65320 $$2Author$$achronocoulometry
000040430 7001_ $$0P:(DE-HGF)0$$aWang, J. X.$$b1
000040430 7001_ $$0P:(DE-HGF)0$$aOcko, B. M.$$b2
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