001     40430
005     20240610115900.0
024 7 _ |2 DOI
|a 10.1016/S0022-0728(00)00380-6
024 7 _ |2 WOS
|a WOS:000168192000046
037 _ _ |a PreJuSER-40430
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Analytical
084 _ _ |2 WoS
|a Electrochemistry
100 1 _ |a Wandlowski, T.
|0 P:(DE-Juel1)VDB5443
|b 0
|u FZJ
245 _ _ |a Adsorption of bromide at the Ag(100) electrode surface
260 _ _ |a New York, NY [u.a.]
|b Elsevier
|c 2001
300 _ _ |a 418
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|0 0
|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |a Journal of Electroanalytical Chemistry
|x 0022-0728
|0 3261
|v 500
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The adsorption and phase formation of bromide on Ag(100) has been studied by chronocoulometry and surface X-ray scattering (SXS). With increasing electrode potential, bromide undergoes a phase transition from a lattice gas to an ordered c(2 x 2) structure (theta = 0.5). The degree of lateral disorder was estimated by comparing the SXS- and the electrochemical measurements. Based on chronocoulometric experiments, a thermodynamic analysis of charge density data was performed to describe the bromide adsorption at the Ag(100) electrode. The Gibbs surfaces excess, electrosorption valencies, Esin-Markov coefficients, and the Gibbs energy of adsorption, lateral interaction energies as well as surface dipole moments have been estimated. The experimental theta versus E- isotherms are modeled employing (i) a quasi-chemical approximation as well as (ii) the results of a recent Monte Carlo simulation. An attempt is made to discuss the structure data and thermodynamic quantities of bromide adsorption on Ag(100) on the basis of the Grahame-Parsons model of the Helmholtz layer. (C) 2001 Elsevier Science B.V. All rights reserved.
536 _ _ |a Struktur und Dynamik von Grenzflächen
|c 29.25.0
|2 G:(DE-HGF)
|0 G:(DE-Juel1)FUEK60
|x 0
588 _ _ |a Dataset connected to Web of Science
650 _ 7 |a J
|2 WoSType
653 2 0 |2 Author
|a bromide adsorption
653 2 0 |2 Author
|a Ag(100) electrodes
653 2 0 |2 Author
|a chronocoulometry
700 1 _ |a Wang, J. X.
|0 P:(DE-HGF)0
|b 1
700 1 _ |a Ocko, B. M.
|0 P:(DE-HGF)0
|b 2
773 _ _ |a 10.1016/S0022-0728(00)00380-6
|g Vol. 500, p. 418
|p 418
|q 500<418
|0 PERI:(DE-600)1491150-4
|t Journal of electroanalytical chemistry
|v 500
|y 2001
|x 0022-0728
909 C O |o oai:juser.fz-juelich.de:40430
|p VDB
913 1 _ |k 29.25.0
|v Struktur und Dynamik von Grenzflächen
|l Grenzflächen- und Vakuumforschung
|b Struktur der Materie und Materialforschung
|0 G:(DE-Juel1)FUEK60
|x 0
914 1 _ |y 2001
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |k ISG-3
|l Institut für Grenzflächen und Vakuumtechnologien
|d 31.12.2006
|g ISG
|0 I:(DE-Juel1)VDB43
|x 0
920 1 _ |k IFF-IMF
|l Mikrostrukturforschung
|d 31.12.2006
|g IFF
|0 I:(DE-Juel1)VDB37
|x 1
970 _ _ |a VDB:(DE-Juel1)5422
980 _ _ |a VDB
980 _ _ |a ConvertedRecord
980 _ _ |a journal
980 _ _ |a I:(DE-Juel1)PGI-3-20110106
980 _ _ |a I:(DE-Juel1)PGI-5-20110106
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)ER-C-1-20170209
981 _ _ |a I:(DE-Juel1)PGI-3-20110106
981 _ _ |a I:(DE-Juel1)PGI-5-20110106


LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21