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024 | 7 | _ | |2 DOI |a 10.1016/S0022-0728(00)00380-6 |
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037 | _ | _ | |a PreJuSER-40430 |
041 | _ | _ | |a eng |
082 | _ | _ | |a 540 |
084 | _ | _ | |2 WoS |a Chemistry, Analytical |
084 | _ | _ | |2 WoS |a Electrochemistry |
100 | 1 | _ | |a Wandlowski, T. |0 P:(DE-Juel1)VDB5443 |b 0 |u FZJ |
245 | _ | _ | |a Adsorption of bromide at the Ag(100) electrode surface |
260 | _ | _ | |a New York, NY [u.a.] |b Elsevier |c 2001 |
300 | _ | _ | |a 418 |
336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
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336 | 7 | _ | |a article |2 DRIVER |
440 | _ | 0 | |a Journal of Electroanalytical Chemistry |x 0022-0728 |0 3261 |v 500 |
500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
520 | _ | _ | |a The adsorption and phase formation of bromide on Ag(100) has been studied by chronocoulometry and surface X-ray scattering (SXS). With increasing electrode potential, bromide undergoes a phase transition from a lattice gas to an ordered c(2 x 2) structure (theta = 0.5). The degree of lateral disorder was estimated by comparing the SXS- and the electrochemical measurements. Based on chronocoulometric experiments, a thermodynamic analysis of charge density data was performed to describe the bromide adsorption at the Ag(100) electrode. The Gibbs surfaces excess, electrosorption valencies, Esin-Markov coefficients, and the Gibbs energy of adsorption, lateral interaction energies as well as surface dipole moments have been estimated. The experimental theta versus E- isotherms are modeled employing (i) a quasi-chemical approximation as well as (ii) the results of a recent Monte Carlo simulation. An attempt is made to discuss the structure data and thermodynamic quantities of bromide adsorption on Ag(100) on the basis of the Grahame-Parsons model of the Helmholtz layer. (C) 2001 Elsevier Science B.V. All rights reserved. |
536 | _ | _ | |a Struktur und Dynamik von Grenzflächen |c 29.25.0 |2 G:(DE-HGF) |0 G:(DE-Juel1)FUEK60 |x 0 |
588 | _ | _ | |a Dataset connected to Web of Science |
650 | _ | 7 | |a J |2 WoSType |
653 | 2 | 0 | |2 Author |a bromide adsorption |
653 | 2 | 0 | |2 Author |a Ag(100) electrodes |
653 | 2 | 0 | |2 Author |a chronocoulometry |
700 | 1 | _ | |a Wang, J. X. |0 P:(DE-HGF)0 |b 1 |
700 | 1 | _ | |a Ocko, B. M. |0 P:(DE-HGF)0 |b 2 |
773 | _ | _ | |a 10.1016/S0022-0728(00)00380-6 |g Vol. 500, p. 418 |p 418 |q 500<418 |0 PERI:(DE-600)1491150-4 |t Journal of electroanalytical chemistry |v 500 |y 2001 |x 0022-0728 |
909 | C | O | |o oai:juser.fz-juelich.de:40430 |p VDB |
913 | 1 | _ | |k 29.25.0 |v Struktur und Dynamik von Grenzflächen |l Grenzflächen- und Vakuumforschung |b Struktur der Materie und Materialforschung |0 G:(DE-Juel1)FUEK60 |x 0 |
914 | 1 | _ | |y 2001 |
915 | _ | _ | |0 StatID:(DE-HGF)0010 |a JCR/ISI refereed |
920 | 1 | _ | |k ISG-3 |l Institut für Grenzflächen und Vakuumtechnologien |d 31.12.2006 |g ISG |0 I:(DE-Juel1)VDB43 |x 0 |
920 | 1 | _ | |k IFF-IMF |l Mikrostrukturforschung |d 31.12.2006 |g IFF |0 I:(DE-Juel1)VDB37 |x 1 |
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980 | _ | _ | |a UNRESTRICTED |
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981 | _ | _ | |a I:(DE-Juel1)PGI-3-20110106 |
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