001     4078
005     20240619083306.0
024 7 _ |2 pmid
|a pmid:19166277
024 7 _ |2 DOI
|a 10.1021/la8029903
024 7 _ |2 WOS
|a WOS:000263373600078
037 _ _ |a PreJuSER-4078
041 _ _ |a eng
082 _ _ |a 670
084 _ _ |2 WoS
|a Chemistry, Multidisciplinary
084 _ _ |2 WoS
|a Chemistry, Physical
084 _ _ |2 WoS
|a Materials Science, Multidisciplinary
100 1 _ |0 P:(DE-HGF)0
|a Zhang, Z.
|b 0
245 _ _ |a Reversible gelation of rod-like viruses grafted with thermoresponsive polymers
260 _ _ |a Washington, DC
|b ACS Publ.
|c 2009
300 _ _ |a 2437 - 2442
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|0 0
|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |0 4081
|a Langmuir
|v 25
|x 0743-7463
|y 4
500 _ _ |a This work was supported by the European network of excellence-SoftComp. The EU is also acknowledged for funding through Nanodirect FP7-NMP-2007-SMALL-1, project 213948. We also thank Sabine Willbold for performing NMR measurement and Johan Buitenhuis for useful discussion. Jan K. Dhont is acknowledged for stimulating discussions and for his reading of the manuscript.
520 _ _ |a The synthesis and selected macroscopic properties of a new model system consisting of poly(N-isopropylacrylamide) (PNIPAM)-coated rod-like fd virus particles are presented. The sticky rod-like colloids can be used to study effect of particle shape on gelation transition, the structure and viscoelasticity of isotropic and nematic gels, and to make both open isotropic as well as ordered nematic particle networks. This model system of rod-like colloids, for which the strength of attraction between the particles is tunable, is obtained by chemically grafting highly monodisperse rod-like fd virus particles with thermoresponsive polymers, e.g. PNIPAM. At room temperature, suspensions of the resulting hybrid PNIPAM-fd are fluid sols which are in isotropic or liquid crystalline phases, depending on the particle concentration and ionic strength. During heating/cooling, the suspensions change reversibly between sol and gel state near a critical temperature of approximately 32 degrees C, close to the lower critical solution temperature of free PNIPAM. The so-called nematic gel, which exhibits a cholesteric feature, can therefore be easily obtained. The gelation behavior of PNIPAM-fd system and the structure of the nematic gel have been characterized by rheology, optical microscopy and small-angle X-ray scattering.
536 _ _ |a Kondensierte Materie
|0 G:(DE-Juel1)FUEK414
|c P54
|2 G:(DE-HGF)
|x 0
536 _ _ |a NANODIRECT - Toolbox for Directed and Controlled Self-Assembly of nano-Colloids (213948)
|0 G:(EU-Grant)213948
|c 213948
|x 1
|f FP7-NMP-2007-SMALL-1
588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Acrylamides: chemistry
650 _ 2 |2 MeSH
|a Gelatin: chemistry
650 _ 2 |2 MeSH
|a Gels: chemistry
650 _ 2 |2 MeSH
|a Liquid Crystals: chemistry
650 _ 2 |2 MeSH
|a Molecular Structure
650 _ 2 |2 MeSH
|a Phase Transition
650 _ 2 |2 MeSH
|a Polymers: chemistry
650 _ 2 |2 MeSH
|a Temperature
650 _ 2 |2 MeSH
|a Viruses: chemistry
650 _ 7 |0 0
|2 NLM Chemicals
|a Acrylamides
650 _ 7 |0 0
|2 NLM Chemicals
|a Gels
650 _ 7 |0 0
|2 NLM Chemicals
|a Polymers
650 _ 7 |0 0
|2 NLM Chemicals
|a poly(N-isopropylacrylamide)
650 _ 7 |0 9000-70-8
|2 NLM Chemicals
|a Gelatin
650 _ 7 |2 WoSType
|a J
700 1 _ |0 P:(DE-HGF)0
|a Krishna, N.
|b 1
700 1 _ |0 P:(DE-Juel1)130797
|a Lettinga, M. P.
|b 2
|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Vermant, J.
|b 3
700 1 _ |0 P:(DE-HGF)0
|a Grelet, E.
|b 4
773 _ _ |0 PERI:(DE-600)2005937-1
|a 10.1021/la8029903
|g Vol. 25, p. 2437 - 2442
|p 2437 - 2442
|q 25<2437 - 2442
|t Langmuir
|v 25
|x 0743-7463
|y 2009
856 7 _ |u http://dx.doi.org/10.1021/la8029903
909 C O |o oai:juser.fz-juelich.de:4078
|p openaire
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913 1 _ |0 G:(DE-Juel1)FUEK414
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|v Kondensierte Materie
|x 0
|z entfällt bis 2009
914 1 _ |y 2009
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |0 I:(DE-Juel1)VDB787
|d 31.12.2010
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|l Weiche Materie
|x 0
970 _ _ |a VDB:(DE-Juel1)110742
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