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000040855 0247_ $$2DOI$$a10.1029/2004GL020089
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000040855 084__ $$2WoS$$aGeosciences, Multidisciplinary
000040855 1001_ $$0P:(DE-HGF)0$$aAnderson, R. S.$$b0
000040855 245__ $$aCarbon kinetic isotope effects in the gas-phase reactions of aromatic hydrocarbons with the OH radical at 296 ± 4 K
000040855 260__ $$aWashington, DC$$bAmerican Geophysical Union$$c2004
000040855 300__ $$aL15108
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000040855 440_0 $$02249$$aGeophysical Research Letters$$v31$$x0094-8276
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000040855 520__ $$aThe carbon kinetic isotope effects (KIEs) of the room temperature reactions of benzene and several light alkyl benzenes with OH radicals were studied in a reaction chamber at ambient pressure using gas chromatography coupled with online combustion and isotope ratio mass spectrometry (GCC-IRMS). The KIEs are reported in per mil according to epsilon (parts per thousand)=(KIE-1) x 1000, where KIE=k(12)/k(13). The following average KIEs were obtained, (all in parts per thousand): benzene 7.53+/-0.50; toluene 5.95+/-0.28; ethylbenzene 4.34+/-0.28; o-xylene 4.27+/-0.05, p-xylene 4.83+/-0.81; o-ethyltoluene 4.71+/-0.12 and 1,2,4-trimethylbenzene 3.18+/-0.09. Our KIE value for benzene + OH agrees with the only reported value known to us [Rudolph et al., 2000]. It is shown that measurements of the stable carbon isotope ratios of light aromatic compounds should be extremely useful to study atmospheric processing by the OH radical.
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000040855 7001_ $$0P:(DE-Juel1)VDB25516$$aIannone, R.$$b1$$uFZJ
000040855 7001_ $$0P:(DE-HGF)0$$aThompson, A. E.$$b2
000040855 7001_ $$0P:(DE-Juel1)VDB1361$$aRudolph, J.$$b3$$uFZJ
000040855 7001_ $$0P:(DE-HGF)0$$aHuang, L.$$b4
000040855 773__ $$0PERI:(DE-600)2021599-X$$a10.1029/2004GL020089$$gVol. 31, p. L15108$$pL15108$$q31<L15108$$tGeophysical research letters$$v31$$x0094-8276$$y2004
000040855 8567_ $$uhttp://dx.doi.org/10.1029/2004GL020089
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