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@ARTICLE{Anderson:40855,
author = {Anderson, R. S. and Iannone, R. and Thompson, A. E. and
Rudolph, J. and Huang, L.},
title = {{C}arbon kinetic isotope effects in the gas-phase reactions
of aromatic hydrocarbons with the {OH} radical at 296 ± 4
{K}},
journal = {Geophysical research letters},
volume = {31},
issn = {0094-8276},
address = {Washington, DC},
publisher = {American Geophysical Union},
reportid = {PreJuSER-40855},
pages = {L15108},
year = {2004},
note = {Record converted from VDB: 12.11.2012},
abstract = {The carbon kinetic isotope effects (KIEs) of the room
temperature reactions of benzene and several light alkyl
benzenes with OH radicals were studied in a reaction chamber
at ambient pressure using gas chromatography coupled with
online combustion and isotope ratio mass spectrometry
(GCC-IRMS). The KIEs are reported in per mil according to
epsilon (parts per thousand)=(KIE-1) x 1000, where
KIE=k(12)/k(13). The following average KIEs were obtained,
(all in parts per thousand): benzene 7.53+/-0.50; toluene
5.95+/-0.28; ethylbenzene 4.34+/-0.28; o-xylene 4.27+/-0.05,
p-xylene 4.83+/-0.81; o-ethyltoluene 4.71+/-0.12 and
1,2,4-trimethylbenzene 3.18+/-0.09. Our KIE value for
benzene + OH agrees with the only reported value known to us
[Rudolph et al., 2000]. It is shown that measurements of the
stable carbon isotope ratios of light aromatic compounds
should be extremely useful to study atmospheric processing
by the OH radical.},
keywords = {J (WoSType)},
cin = {ICG-II},
ddc = {550},
cid = {I:(DE-Juel1)VDB48},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Geosciences, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000223342300003},
doi = {10.1029/2004GL020089},
url = {https://juser.fz-juelich.de/record/40855},
}