Hauptseite > Publikationsdatenbank > Carbon kinetic isotope effects in the gas-phase reactions of aromatic hydrocarbons with the OH radical at 296 ± 4 K > print

001     40855
005     20240712101054.0
024 7 _ |a 10.1029/2004GL020089
|2 DOI
024 7 _ |a WOS:000223342300003
|2 WOS
024 7 _ |a 2128/20818
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037 _ _ |a PreJuSER-40855
041 _ _ |a eng
082 _ _ |a 550
084 _ _ |2 WoS
|a Geosciences, Multidisciplinary
100 1 _ |a Anderson, R. S.
|b 0
|0 P:(DE-HGF)0
245 _ _ |a Carbon kinetic isotope effects in the gas-phase reactions of aromatic hydrocarbons with the OH radical at 296 ± 4 K
260 _ _ |a Washington, DC
|b American Geophysical Union
|c 2004
300 _ _ |a L15108
336 7 _ |a Journal Article
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336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
|2 DRIVER
440 _ 0 |a Geophysical Research Letters
|x 0094-8276
|0 2249
|v 31
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The carbon kinetic isotope effects (KIEs) of the room temperature reactions of benzene and several light alkyl benzenes with OH radicals were studied in a reaction chamber at ambient pressure using gas chromatography coupled with online combustion and isotope ratio mass spectrometry (GCC-IRMS). The KIEs are reported in per mil according to epsilon (parts per thousand)=(KIE-1) x 1000, where KIE=k(12)/k(13). The following average KIEs were obtained, (all in parts per thousand): benzene 7.53+/-0.50; toluene 5.95+/-0.28; ethylbenzene 4.34+/-0.28; o-xylene 4.27+/-0.05, p-xylene 4.83+/-0.81; o-ethyltoluene 4.71+/-0.12 and 1,2,4-trimethylbenzene 3.18+/-0.09. Our KIE value for benzene + OH agrees with the only reported value known to us [Rudolph et al., 2000]. It is shown that measurements of the stable carbon isotope ratios of light aromatic compounds should be extremely useful to study atmospheric processing by the OH radical.
536 _ _ |a Chemie und Dynamik der Geo-Biosphäre
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588 _ _ |a Dataset connected to Web of Science
650 _ 7 |a J
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700 1 _ |a Iannone, R.
|b 1
|u FZJ
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700 1 _ |a Thompson, A. E.
|b 2
|0 P:(DE-HGF)0
700 1 _ |a Rudolph, J.
|b 3
|u FZJ
|0 P:(DE-Juel1)VDB1361
700 1 _ |a Huang, L.
|b 4
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773 _ _ |a 10.1029/2004GL020089
|g Vol. 31, p. L15108
|p L15108
|q 31|0 PERI:(DE-600)2021599-X
|t Geophysical research letters
|v 31
|y 2004
|x 0094-8276
856 7 _ |u http://dx.doi.org/10.1029/2004GL020089
856 4 _ |u https://juser.fz-juelich.de/record/40855/files/2004GL020089.pdf
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/40855/files/2004GL020089.pdf?subformat=pdfa
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913 1 _ |k U01
|v Chemie und Dynamik der Geo-Biosphäre
|l Chemie und Dynamik der Geo-Biosphäre
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914 1 _ |y 2004
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915 _ _ |a JCR/ISI refereed
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920 1 _ |k ICG-II
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981 _ _ |a I:(DE-Juel1)IEK-8-20101013

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