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@ARTICLE{Wang:40949,
      author       = {Wang, H. and Elsebrock, R. and Schneller, T. and Waser, R.
                      and Yao, X.},
      title        = {{B}ismuth zinc niobate ({B}i1.5{Z}n{N}b1.5{O}7) ceramics
                      derived from metallo-organic decomposition precursor
                      solution},
      journal      = {Solid state communications},
      volume       = {132},
      issn         = {0038-1098},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {PreJuSER-40949},
      pages        = {481 - 486},
      year         = {2004},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The preparation, microstructure development and dielectric
                      properties of Bi1.5ZnNb1.5O7 pyrochlore ceramics by
                      metalloorganic decomposition (MOD) route are reported.
                      Homogeneous precalcined ceramic powders of 13-36 nm
                      crystallite size were obtained at temperatures ranging from
                      500 to 700degreesC. The thermal decomposition/oxidation of
                      the gelled precursor solution was chemically analyzed,
                      TG/DTA, XRD, and SEM, led to the formation of a pure cubic
                      pyrochlore phase with a stoichiometry close to
                      Bi1.5ZnNb1.5O7 which begins to form at 500degreesC. The
                      metallo-organic precursor synthesis method, where Bi, Zn and
                      Nb ions are chelated to form metal complexes, allows the
                      control of Bi/Zn/Nb stoichiornetric ratio on a molecular
                      scale leading to the rapid formation of bismuth zinc niobate
                      (Bi1.5ZnNb1.5O7) ceramic fine powders with pure pyrochlore
                      structure. The powders were pressed into pellets and can be
                      sintered at temperatures as low as 800-1000degreesC. Fine
                      crystalline ceramics with the grain size in the range of
                      200-500 nm have been obtained at the sintering temperature
                      of 800degreesC. The dielectric Properties in high frequency
                      to microwave range were measured and discussed. (C) 2004
                      Elsevier Ltd. All rights reserved.},
      keywords     = {J (WoSType)},
      cin          = {IFF-IEM},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB321},
      pnm          = {Kondensierte Materie},
      pid          = {G:(DE-Juel1)FUEK242},
      shelfmark    = {Physics, Condensed Matter},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000224867300011},
      doi          = {10.1016/j.ssc.2004.07.071},
      url          = {https://juser.fz-juelich.de/record/40949},
}