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000004117 0247_ $$2DOI$$a10.1016/j.envpol.2009.01.026
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000004117 084__ $$2WoS$$aEnvironmental Sciences
000004117 1001_ $$0P:(DE-HGF)0$$aZhang, H.$$b0
000004117 245__ $$aDegradation of a chiral nonylphenol isomer in two agricultural soils
000004117 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2009
000004117 300__ $$a1904 - 1910
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000004117 440_0 $$08083$$aEnvironmental Pollution$$v157$$x0269-7491$$y6
000004117 500__ $$aThis study has been performed within the frame of the priority program SPP 1315 "Biogeochemical Interfaces in Soil", funded by the German Science Foundation [Deutsche Forschungsgemeinschaft (DFG)], to whom the authors are deeply grateful.
000004117 520__ $$aThe degradation of a chiral nonylphenol isomer, 4-(1-ethyl-1,4-dimethylpentyl)phenol (NP(112)), in two agricultural soils from Monheim and Dortmund, Germany has been studied. The degradation of NP(112) and the formation of a nitro-nonylphenol metabolite were determined by means of GC-MS analysis. The degradation followed bi-exponential order kinetics, with half-life of less than 5 days in both soils. The nitro-metabolite was found at different concentration levels in the two soils. The nitro-metabolite of NP(112) was more persistent than its parent compound. After 150 days about 13% of the initially applied NP(112) remained in the Monheim soil as its nitro-metabolite. Results of the E-screen assay revealed that the nitro-NP(112) has oestrogenic potency of 85% of that of NP(112). Furthermore, the results of chiral GC-MS analysis revealed that no chiral degradation of NP(112) occurred in this study.
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000004117 650_2 $$2MeSH$$aAgriculture
000004117 650_2 $$2MeSH$$aBiodegradation, Environmental
000004117 650_2 $$2MeSH$$aEcology: methods
000004117 650_2 $$2MeSH$$aEndocrine Disruptors: analysis
000004117 650_2 $$2MeSH$$aGas Chromatography-Mass Spectrometry
000004117 650_2 $$2MeSH$$aGermany
000004117 650_2 $$2MeSH$$aHalf-Life
000004117 650_2 $$2MeSH$$aHydrogen-Ion Concentration
000004117 650_2 $$2MeSH$$aModels, Chemical
000004117 650_2 $$2MeSH$$aPhenols: analysis
000004117 650_2 $$2MeSH$$aSoil: analysis
000004117 650_2 $$2MeSH$$aSoil Microbiology
000004117 650_2 $$2MeSH$$aStereoisomerism
000004117 650_7 $$00$$2NLM Chemicals$$aEndocrine Disruptors
000004117 650_7 $$00$$2NLM Chemicals$$aPhenols
000004117 650_7 $$00$$2NLM Chemicals$$aSoil
000004117 650_7 $$025154-52-3$$2NLM Chemicals$$anonylphenol
000004117 650_7 $$2WoSType$$aJ
000004117 65320 $$2Author$$aNitro-NP
000004117 65320 $$2Author$$aPersistent metabolite
000004117 65320 $$2Author$$aEstrogenic potency
000004117 65320 $$2Author$$aE-screen
000004117 65320 $$2Author$$aChiral GC-MS
000004117 7001_ $$0P:(DE-HGF)0$$aSpiteller, M.$$b1
000004117 7001_ $$0P:(DE-Juel1)VDB40956$$aGuenther, K.$$b2$$uFZJ
000004117 7001_ $$0P:(DE-HGF)0$$aBoehmler, G.$$b3
000004117 7001_ $$0P:(DE-HGF)0$$aZuehlke, S.$$b4
000004117 773__ $$0PERI:(DE-600)2013037-5$$a10.1016/j.envpol.2009.01.026$$gVol. 157, p. 1904 - 1910$$p1904 - 1910$$q157<1904 - 1910$$tEnvironmental pollution$$v157$$x0269-7491$$y2009
000004117 8567_ $$uhttp://dx.doi.org/10.1016/j.envpol.2009.01.026
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000004117 9141_ $$y2009
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