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@ARTICLE{Schmitz:4174,
author = {Schmitz, C. H. and Rang, C. and Bai, Y. and Kossev, I. and
Ikonomov, J. and Su, Y. and Kotsis, K. and Soubatch, S. and
Neucheva, O. and Tautz, F. S. and Neese, F. and Steinrück,
H.-P. and Gottfried, J.M. and Dötz, K. H. and Sokolowski,
M.},
title = {{A} {C}omparative {S}tudy of a {T}riphenylene {T}ricarbonyl
{C}hromium {C}omplex and {I}ts {U}ncoordinated {A}rene
{L}igand on the {A}g(111) {S}urface: {I}nfluence of the
{C}omplexation on the {A}dsorption},
journal = {The journal of physical chemistry / C},
volume = {113},
issn = {1932-7447},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PreJuSER-4174},
pages = {6014 - 6021},
year = {2009},
note = {Financial support by the Deutsche Forschungsgemeinschaft
through SFB 624 "From the Design of Chemical Templates
towards Reaction Control" and SFB 583 "Redox-Active Metal
Complexes: Control of Reactivity via Molecular Architecture"
is gratefully acknowledged.},
abstract = {An aromatic triphenylene molecule
(2,3-diethyl-1,4-dimethoxytriphenylene; TPH) and its
regioselectively Cr(CO)(3)-labeled complex (eta(6)-( 1
2,3,4,4a,12b)-tricarbonyl(2,3-diethyl-1,4-dimethoxytriphenylene)chromium(0);
alpha-TPHC) were deposited on a Ag(111) surface by vapor
deposition. The monolayers were investigated by X-ray
photoelectron spectroscopy and scanning tunneling
microscopy. Both substances adsorb with the extended
pi-system parallel to the surface and form long-range
ordered monolayers. The Cr(CO)(3) group of the alpha-TPHC
complex is oriented toward the vacuum. Although the
footprints of both substances are similar, the additional
Cr(CO)(3) group on the alpha-TPHC leads to a lateral order
(unit cell) that is significantly different from that of
TPH.},
keywords = {J (WoSType)},
cin = {IBN-3 / JARA-FIT},
ddc = {540},
cid = {I:(DE-Juel1)VDB801 / $I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Chemistry, Physical / Nanoscience $\&$ Nanotechnology /
Materials Science, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000265030200022},
doi = {10.1021/jp810788n},
url = {https://juser.fz-juelich.de/record/4174},
}