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084 | _ | _ | |2 WoS |a Physics, Atomic, Molecular & Chemical |
100 | 1 | _ | |a Belushkin, M. |b 0 |u FZJ |0 P:(DE-Juel1)VDB75398 |
245 | _ | _ | |a Twist grain boundaries in cubic surfactant phases |
260 | _ | _ | |a Melville, NY |b American Institute of Physics |c 2009 |
300 | _ | _ | |a 134712 |
336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
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440 | _ | 0 | |a Journal of Chemical Physics |x 0021-9606 |0 3145 |v 130 |
500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
520 | _ | _ | |a Twist grain boundaries in bicontinuous cubic surfactant phases are studied by employing a Ginzburg-Landau model of ternary amphiphilic systems. Calculations are performed on a discrete real-space lattice with periodic boundary conditions for the lamellar L(alpha), gyroid G, diamond D, and the Schwarz P phases for various twist angles. An isosurface analysis of the scalar order parameter reveals the structure of the surfactant monolayer at the interfaces between the oil-rich and water-rich regions. The curvature distributions show that the grain boundaries are minimal surfaces. The interfacial free energy per unit area is determined as a function of the twist angle for the G, D, P, and lamellar phases using two complementary approaches: the Ginzburg-Landau free-energy functional and a geometrical approach based on the curvature energy of a monolayer. For the L(alpha), G, and D phases the interfacial free energy per unit area is very small, has the same order of magnitude, and exhibits a nonmonotonic dependence on the twist angle. The P phase is found to be unstable with respect to the nucleation of grain boundaries. |
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653 | 2 | 0 | |2 Author |a diamond |
653 | 2 | 0 | |2 Author |a free energy |
653 | 2 | 0 | |2 Author |a Ginzburg-Landau theory |
653 | 2 | 0 | |2 Author |a liquid crystals |
653 | 2 | 0 | |2 Author |a monolayers |
653 | 2 | 0 | |2 Author |a surface energy |
653 | 2 | 0 | |2 Author |a surfactants |
653 | 2 | 0 | |2 Author |a twist boundaries |
700 | 1 | _ | |a Gompper, G. |b 1 |u FZJ |0 P:(DE-Juel1)130665 |
773 | _ | _ | |a 10.1063/1.3096987 |g Vol. 130, p. 134712 |p 134712 |q 130<134712 |0 PERI:(DE-600)1473050-9 |t The @journal of chemical physics |v 130 |y 2009 |x 0021-9606 |
856 | 7 | _ | |u http://dx.doi.org/10.1063/1.3096987 |
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