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@ARTICLE{Bloss:42774,
      author       = {Bloss, W. J. and Lee, J. D. and Bloss, C. and Heard, D. E.
                      and Pilling, M. J. and Wirtz, K. and Martin-Reviejo, M. and
                      Siese, M.},
      title        = {{V}alidation of the calibration of a laser-induced
                      fluorescence instrument for the measurement of {OH} radicals
                      in the atmosphere},
      journal      = {Atmospheric chemistry and physics},
      volume       = {4},
      issn         = {1680-7316},
      address      = {Katlenburg-Lindau},
      publisher    = {EGU},
      reportid     = {PreJuSER-42774},
      pages        = {571 - 583},
      year         = {2004},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {An assessment of the accuracy of OH concentrations measured
                      in a smog chamber by a calibrated laser-induced fluorescence
                      (LIF) instrument has been made, in the course of 9
                      experiments performed to study the photo-oxidation of
                      benzene, toluene, 1,3,5-trimethylbenzene, paraxylene,
                      ortho-cresol and ethene at the European Photoreactor
                      facility (EUPHORE). The LIF system was calibrated via the
                      water photolysis/ozone actinometry approach. OH
                      concentrations were inferred from the instantaneous rate of
                      removal of each hydrocarbon species (measured by FTIR or
                      HPLC) via the appropriate rate coefficient for their
                      reaction with OH, and compared with those obtained from the
                      LIF system. Good agreement between the two approaches was
                      found for all species with the exception of
                      1,3,5-trimethylbenzene, for which OH concentrations inferred
                      from hydrocarbon removal were a factor of 3 lower than those
                      measured by the LIF system. From the remaining 8
                      experiments, an overall value of 1.15+/-0.13 (+/-1sigma) was
                      obtained for [OH](LIF)/[OH](HydrocarbonDecay), compared with
                      the estimated uncertainty in the accuracy of the water
                      photolysis/ozone actinometry OH calibration technique of
                      $26\%$ (1sigma).},
      keywords     = {J (WoSType)},
      cin          = {ICG-II},
      ddc          = {550},
      cid          = {I:(DE-Juel1)VDB48},
      pnm          = {Chemie und Dynamik der Geo-Biosphäre},
      pid          = {G:(DE-Juel1)FUEK257},
      shelfmark    = {Meteorology $\&$ Atmospheric Sciences},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000220723300001},
      url          = {https://juser.fz-juelich.de/record/42774},
}