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@ARTICLE{Maassen:42897,
author = {Maassen, R. and Eisenriegler, E. and Bringer, A.},
title = {{D}ensity depletion profile and solvation free energy of a
colloidal particle in a polymer solution},
journal = {The journal of chemical physics},
volume = {115},
issn = {0021-9606},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {PreJuSER-42897},
pages = {5292 - 5309},
year = {2001},
note = {Record converted from VDB: 12.11.2012},
abstract = {The solvation free energy and polymer density depletion
profile of a single mesoscopic colloidal particle in a
solution of free nonadsorbing polymer chains are
investigated theoretically. Keeping both the particle to
polymer size ratio and the degree of inter-chain overlap
arbitrary, we see how the qualitatively different behavior
evolves in the limits of small and large size ratios and of
dilute and semidilute solutions. While most of our results
are obtained within a mean-field approach, we also use a
"renormalized tree approximation" to estimate the surface
tension and the coefficient of spontaneous curvature in a
Helfrich expansion for large particle to polymer size ratio.
There is a weak maximum in the polymer density profile for
arbitrary size ratio. For small size ratio the maximum can
be explained in terms of a minimum in the bulk polymer
density correlation function. (C) 2001 American Institute of
Physics.},
keywords = {J (WoSType)},
cin = {IFF-TH-I / IFF-TH-II},
ddc = {540},
cid = {I:(DE-Juel1)VDB30 / I:(DE-Juel1)VDB31},
pnm = {Elektronische Struktur von Festkörpern, Oberflächen und
Schichtsystemen / Polymere, Membranen und komplexe
Flüssigkeiten},
pid = {G:(DE-Juel1)FUEK52 / G:(DE-Juel1)FUEK53},
shelfmark = {Physics, Atomic, Molecular $\&$ Chemical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000170991200041},
doi = {10.1063/1.1394206},
url = {https://juser.fz-juelich.de/record/42897},
}