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@ARTICLE{Samoilov:42960,
author = {Samoilov, V. N. and Sivebaek, I. M. and Persson, B. N. J.},
title = {{T}he effect of surface roughness on the adhesion of solid
surfaces for systems with and without liquid lubricant},
journal = {The journal of chemical physics},
volume = {121},
issn = {0021-9606},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {PreJuSER-42960},
pages = {9639 - 9647},
year = {2004},
note = {Record converted from VDB: 12.11.2012},
abstract = {We present molecular dynamics results for the interaction
between two solid elastic walls during pull-off for systems
with and without octane (C(8)H(18)) lubricant. We used two
types of substrate--flat and corrugated--and varied the
lubricant coverage from approximately 1/8 to approximately 4
ML (monolayers) of octane. For the flat substrate without
lubricant the maximum adhesion was found to be approximately
three times larger than for the system with the corrugated
substrate. As a function of the octane coverage (for the
corrugated substrate) the pull-off force first increases as
the coverage increases from 0 to approximately 1 ML, and
then decreases as the coverage is increased beyond monolayer
coverage. It is shown that at low octane coverage, the
octane molecules located in the substrate corrugation wells
during squeezing are pulled out of the wells during
pull-off, forming a network of nanocapillary bridges around
the substrate nanoasperities, thus increasing the adhesion
between two surfaces. For greater lubricant coverages a
single capillary bridge is formed. The adhesion force
saturates for lubricant coverages greater than 3 ML. For the
flat substrate, during pull-off we observe discontinuous,
thermally activated changes in the number n of lubricant
layers (n-1-->n layering transitions), whereas for the
corrugated substrate these transitions are "averaged" by the
substrate surface roughness.},
keywords = {J (WoSType)},
cin = {IFF-TH-I},
ddc = {540},
cid = {I:(DE-Juel1)VDB30},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK242},
shelfmark = {Physics, Atomic, Molecular $\&$ Chemical},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:15538886},
UT = {WOS:000224895000047},
doi = {10.1063/1.1806814},
url = {https://juser.fz-juelich.de/record/42960},
}