% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Iannone:43163,
      author       = {Iannone, R. and Anderson, R. S. and Vogel, A. and Rudolph,
                      J. and Eby, P. and Whiticar, M. J.},
      title        = {{L}aboratory studies of the hydrogen kinetic isotope
                      effects ({KIE}s) for the reaction of non-methane
                      hydrocarbons with the {OH} radical in the gas phase},
      journal      = {Journal of atmospheric chemistry},
      volume       = {47},
      issn         = {0167-7764},
      address      = {Dordrecht [u.a.]},
      publisher    = {Springer Science + Business Media B.V},
      reportid     = {PreJuSER-43163},
      pages        = {191 - 208},
      year         = {2004},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The hydrogen kinetic isotope effects (KIEs) of the
                      reactions of 15 non-methane hydrocarbons (NMHCs) with the OH
                      radical were measured at 298 +/- 2 K. The measurements were
                      made using NMHCs without artificial isotopic labeling or
                      enrichment. The following average hydrogen KIE values, in
                      per mil (parts per thousand), were obtained: 29.8 +/- 2.1
                      (toluene), 51.6 +/- 2.1 (n-butane), 97.3 +/- 12.5
                      (i-butane), 63.2 +/- 5.9 (cyclopentane), 10.5 (p-xylene),
                      26.8 +/- 3.5 (ethylbenzene), 65.9 +/- 7.0 (n-pentane), 79.5
                      +/- 9.6 (cyclohexane), 52.8 +/- 5.0 (n-hexane), 38.9 +/- 7.8
                      (n-heptane), 33.4 +/- 3.1 (n-octane), 29.6 +/- 1.6
                      (n-nonane), and 29.0 +/- 5.3 (n-decane). The KIEs for
                      reactions of two alkenes ( cyclohexene and 1-heptene) could
                      not be determined accurately due to interference from
                      reaction with ozone, but nevertheless the results clearly
                      show that the KIEs for reaction of alkenes with OH are
                      significantly lower than those for saturated hydrocarbons.
                      The KIEs for reaction of alkanes are smaller than isotope
                      effects reported in literature for the reactions of NMHCs
                      artificially labeled with deuterium. The main reason for
                      this difference is the reduced probability for reaction at a
                      labeled site for compounds with close to natural deuterium
                      abundance, although some impact of secondary isotope effects
                      cannot be ruled out. Still, the KIEs for NMHCs with natural
                      or close to natural abundance of deuterium are of sufficient
                      magnitude to allow determination of the extent of chemical
                      processing of hydrocarbons in the atmosphere using methods
                      analogous to stable carbon KIE studies. Furthermore, it is
                      shown that combining stable hydrogen and stable carbon
                      isotope ratio data has the potential to also provide
                      valuable information regarding the stable isotope ratios of
                      emissions, and specifically to test one of the key
                      assumptions of the stable isotope hydrocarbon clock, the
                      absence of significant variations of the stable isotope
                      ratio for the emitted NMHCs.},
      keywords     = {J (WoSType)},
      cin          = {ICG-II},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB48},
      pnm          = {Chemie und Dynamik der Geo-Biosphäre},
      pid          = {G:(DE-Juel1)FUEK257},
      shelfmark    = {Environmental Sciences / Meteorology $\&$ Atmospheric
                      Sciences},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000220397700005},
      doi          = {10.1023/B:JOCH.0000021035.49613.f7},
      url          = {https://juser.fz-juelich.de/record/43163},
}