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005     20200423202502.0
024 7 _ |2 pmid
|a pmid:19264386
024 7 _ |2 DOI
|a 10.1016/j.envpol.2009.02.004
024 7 _ |2 WOS
|a WOS:000266350800020
024 7 _ |2 Handle
|a 2128/4568
037 _ _ |a PreJuSER-4417
041 _ _ |a eng
082 _ _ |a 333.7
084 _ _ |2 WoS
|a Environmental Sciences
100 1 _ |0 P:(DE-Juel1)129475
|a Jablonowski, N. D.
|b 0
|u FZJ
245 _ _ |a Persistence of 14C-labeled atrazine and its residues on a field lysimeter soil after 22 years
260 _ _ |a Amsterdam [u.a.]
|b Elsevier Science
|c 2009
300 _ _ |a 2126 - 2131
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
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336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |0 8083
|a Environmental Pollution
|v 157
|x 0269-7491
|y 7
500 _ _ |a Sincere thanks are due to Mr. Gunter Henkelmann for the lysimeter soil, and to Mr. Thomas Putz for the transfer of the lysimeters. Analysis of the soil elements in solid samples by Ms. N. Merki and Ms. J. Bachhausen, ZCH, is highly appreciated. The corresponding author Nicolai D. Jablonowski is grateful for support from the German Academic Exchange Service (DAAD), grant No. D/08/42004.
520 _ _ |a Twenty-two years after the last application of ring-14C-labeled atrazine at customary rate (1.7 kg ha(-1)) on an agriculturally used outdoor lysimeter, atrazine is still detectable by means of accelerated solvent extraction and LC-MS/MS analysis. Extractions of the 0-10 cm soil layer yielded 60% of the residual 14C-activity. The extracts contained atrazine (1.0 microg kg(-1)) and 2-hydroxy-atrazine (42.5 microg kg(-1)). Extractions of the material of the lowest layer 55-60 cm consisting of fine gravel yielded 93% of residual 14C-activity, of which 3.4 microg kg(-1) was detected as atrazine and 17.7 microg kg(-1) was 2-hydroxy-atrazine. The detection of atrazine in the lowest layer was of almost four times higher mass than in the upper soil layer. These findings highlight the fact that atrazine is unexpectedly persistent in soil. The overall persistence of atrazine in the environment might represent a potential risk for successive groundwater contamination by leaching even after 22 years of environmental exposure.
536 _ _ |0 G:(DE-Juel1)FUEK407
|2 G:(DE-HGF)
|a Terrestrische Umwelt
|c P24
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588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Agriculture
650 _ 2 |2 MeSH
|a Atrazine: analysis
650 _ 2 |2 MeSH
|a Carbon Radioisotopes: analysis
650 _ 2 |2 MeSH
|a Ecology: methods
650 _ 2 |2 MeSH
|a Herbicides: analysis
650 _ 2 |2 MeSH
|a Mass Spectrometry
650 _ 2 |2 MeSH
|a Soil Pollutants: analysis
650 _ 2 |2 MeSH
|a Time Factors
650 _ 7 |0 0
|2 NLM Chemicals
|a Carbon Radioisotopes
650 _ 7 |0 0
|2 NLM Chemicals
|a Herbicides
650 _ 7 |0 0
|2 NLM Chemicals
|a Soil Pollutants
650 _ 7 |0 1912-24-9
|2 NLM Chemicals
|a Atrazine
650 _ 7 |2 WoSType
|a J
653 2 0 |2 Author
|a Atrazine
653 2 0 |2 Author
|a Persistence
653 2 0 |2 Author
|a Leaching
653 2 0 |2 Author
|a Extraction
653 2 0 |2 Author
|a LC-MS/MS
653 2 0 |2 Author
|a Half-life
653 2 0 |2 Author
|a Bound residues
700 1 _ |0 P:(DE-Juel1)VDB4032
|a Köppchen, S.
|b 1
|u FZJ
700 1 _ |0 P:(DE-Juel1)129471
|a Hofmann, D.
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|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Schäffer, A.
|b 3
700 1 _ |0 P:(DE-Juel1)VDB202
|a Burauel, P.
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773 _ _ |0 PERI:(DE-600)2013037-5
|a 10.1016/j.envpol.2009.02.004
|g Vol. 157, p. 2126 - 2131
|n 7
|p 2126 - 2131
|q 157<2126 - 2131
|t Environmental pollution
|v 157
|x 0269-7491
|y 2009
856 7 _ |u http://dx.doi.org/10.1016/j.envpol.2009.02.004
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