001     44720
005     20180210135323.0
024 7 _ |2 pmid
|a pmid:15749546
024 7 _ |2 DOI
|a 10.1016/j.envpol.2004.10.018
024 7 _ |2 WOS
|a WOS:000227941400015
037 _ _ |a PreJuSER-44720
041 _ _ |a eng
082 _ _ |a 333.7
084 _ _ |2 WoS
|a Environmental Sciences
100 1 _ |a Séquaris, J.-M.
|b 0
|u FZJ
|0 P:(DE-Juel1)VDB9230
245 _ _ |a Equilibrium partitioning of 14C-benzo(a)pyrene and 14C-benazolin between fractionated phases from an arable topsoil
260 _ _ |a Amsterdam [u.a.]
|b Elsevier Science
|c 2005
300 _ _ |a 491 - 500
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
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336 7 _ |a Journal Article
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|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |a Environmental Pollution
|x 0269-7491
|0 8083
|v 135
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Equilibrium partitioning of hydrophobic (14)C-benzo(a)pyrene and hydrophilic (14)C-benazolin between fractionated phases from an arable topsoil of Merzenhausen (Germany) was investigated. Topsoil samples were collected from lysimeters which were incubated with different residual crops. A physical soil fractionation based on sedimentation and centrifugation steps was performed after water extraction. Four soil phases were obtained designated sediment (SED) phase (>20 microm), microaggregate (MA) phase (2 microm-20 microm), colloid (COL) phase (<2 microm) and electrolyte (EL) phase. The distribution of (14)C-benzo(a)pyrene, (14)C-benazolin and organic carbon between the soil phases was established. Enrichment factors for the two chemicals and organic carbon are higher in the COL and MA phases than in the SED phase. The distribution constant K(d) of chemicals for Merzenhausen topsoil was calculated according to two-phase or three-phase partitioning models. The three-phase partitioning model presumes the contribution of the organic carbon for the binding of chemicals. A log K(oc) of 5.55 can be calculated in the case of (14)C-benzo(a)pyrene, which is typical of the hydrophobic association with the soil organic carbon. In the case of (14)C-benazolin, much higher K(d) and K(oc) values were calculated than found with parent molecules after short-time experiments. Long-term aging processes must be considered. Specific effects on the chemical distribution due to the different crop residues were not detected.
536 _ _ |a Chemie und Dynamik der Geo-Biosphäre
|c U01
|2 G:(DE-HGF)
|0 G:(DE-Juel1)FUEK257
|x 0
588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Adsorption
650 _ 2 |2 MeSH
|a Benzo(a)pyrene: chemistry
650 _ 2 |2 MeSH
|a Carbon Radioisotopes
650 _ 2 |2 MeSH
|a Chemical Fractionation: methods
650 _ 2 |2 MeSH
|a Germany
650 _ 2 |2 MeSH
|a Imidazoles: chemistry
650 _ 2 |2 MeSH
|a Mathematics
650 _ 2 |2 MeSH
|a Models, Chemical
650 _ 2 |2 MeSH
|a Soil Pollutants: analysis
650 _ 7 |0 0
|2 NLM Chemicals
|a Carbon Radioisotopes
650 _ 7 |0 0
|2 NLM Chemicals
|a Imidazoles
650 _ 7 |0 0
|2 NLM Chemicals
|a Soil Pollutants
650 _ 7 |0 17692-22-7
|2 NLM Chemicals
|a metizoline
650 _ 7 |0 50-32-8
|2 NLM Chemicals
|a Benzo(a)pyrene
650 _ 7 |a J
|2 WoSType
653 2 0 |2 Author
|a organic chemicals
653 2 0 |2 Author
|a soil phases
653 2 0 |2 Author
|a equilibrium partitioning models
653 2 0 |2 Author
|a crop residues
700 1 _ |a Lavorenti, A.
|b 1
|0 P:(DE-HGF)0
700 1 _ |a Burauel, P.
|b 2
|u FZJ
|0 P:(DE-Juel1)VDB202
773 _ _ |a 10.1016/j.envpol.2004.10.018
|g Vol. 135, p. 491 - 500
|p 491 - 500
|q 135<491 - 500
|0 PERI:(DE-600)2013037-5
|t Environmental pollution
|v 135
|y 2005
|x 0269-7491
856 7 _ |u http://dx.doi.org/10.1016/j.envpol.2004.10.018
909 C O |o oai:juser.fz-juelich.de:44720
|p VDB
913 1 _ |k U01
|v Chemie und Dynamik der Geo-Biosphäre
|l Chemie und Dynamik der Geo-Biosphäre
|b Environment (Umwelt)
|0 G:(DE-Juel1)FUEK257
|x 0
914 1 _ |y 2005
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |k ICG-IV
|l Agrosphäre
|d 31.12.2006
|g ICG
|0 I:(DE-Juel1)VDB50
|x 0
970 _ _ |a VDB:(DE-Juel1)65606
980 _ _ |a VDB
980 _ _ |a ConvertedRecord
980 _ _ |a journal
980 _ _ |a I:(DE-Juel1)IBG-3-20101118
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IBG-3-20101118


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