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@ARTICLE{Wolf:46039,
author = {Wolf, K.-J. and Smeda, A. and Müller, M. and Hilpert, K.},
title = {{I}nvestigations on the {I}nfluence of {A}dditives for
{SO}2 {R}eduction during {H}igh {A}lkaline {B}iomass
{C}ombustion},
journal = {Energy $\&$ fuels},
volume = {19},
issn = {0887-0624},
address = {Columbus, Ohio},
publisher = {American Chemical Society},
reportid = {PreJuSER-46039},
pages = {820 - 824},
year = {2005},
note = {Record converted from VDB: 12.11.2012},
abstract = {Straw and other biomasses can cause severe problems when
used as fuel in combustion systems. Some of the major
problems include high emission of alkalis, HCl, and
especially SO2 to the gas phase. The development of low-cost
primary measures for achieving a SO2 emission below the
European Union (EU) emission limit of 200 mg/Nm(3) without
the need for the installation of a flue gas desulfurization
unit requires an increased understanding of the chemistry of
biomass combustion. For this reason, laboratory combustion
experiments with two different high alkaline (HIAL)
biomasses doped with additives have been conducted in the
temperature range of 800-1100 degrees C. The use of a
high-pressure mass spectrometry (HPMS) sampling technique
allows the on-line specification of combustion byproducts
such as K, Na, S, and Cl species in the combustion flue
gases. The results of the measurements show that the SO2
emission may be related to the K/S and K/Si ratios in the
initial samples. The release of potassium is mostly
dependent on the chlorine content of the samples. Calcium-
and potassium-based additives are able to reduce the release
of SO2 into the gas phase.},
keywords = {J (WoSType)},
cin = {IWV-2},
ddc = {620},
cid = {I:(DE-Juel1)VDB2},
pnm = {Werkstoffsysteme für Kraftwerke},
pid = {G:(DE-Juel1)FUEK248},
shelfmark = {Energy $\&$ Fuels / Engineering, Chemical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000229320700014},
doi = {10.1021/ef040081a},
url = {https://juser.fz-juelich.de/record/46039},
}