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@ARTICLE{Gmann:46286,
author = {Gömann, K. and Borchardt, G. and Schulz, M. and Gömann,
A. and Maus-Friedrichs, W. and Lesage, B. and Kaitasov, O.
and Hoffmann-Eifert, S. and Schneller, T.},
title = {{S}r diffusion in undoped and {L}a-doped {S}r{T}i{O}3
single crystals under oxidizing conditions},
journal = {Physical Chemistry Chemical Physics},
volume = {7},
number = {9},
issn = {1463-9076},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {PreJuSER-46286},
pages = {2053 - 2060},
year = {2005},
note = {Record converted from VDB: 12.11.2012},
abstract = {Strontium titanate SrTiO3(100), (110), and (111) single
crystals, undoped or donor doped with up to 1 $at\%$ La,
were isothermally equilibrated at temperatures between 1523
and 1773 K in synthetic air followed by two different
methods of Sr tracer deposition: ion implantation of Sr-87
and chemical solution deposition of a thin (SrTiO3)-Sr-86
layer. Subsequently, the samples were diffusion annealed
under the same conditions as before. The initial and final
depth profiles were measured by SIMS. For strong La-doping
both tracer deposition methods yield similar Sr diffusion
coefficients, whereas for weak doping the tracer seems to be
immobile in the case of ion implantation. The Sr diffusivity
does not depend on the crystal orientation, but shows strong
dependency on the dopant concentration supporting the defect
chemical model that under oxidizing conditions the donor is
compensated by Sr vacancies. A comparison with literature
data on Sr vacancy, Ti, and La diffusion in this system
confirms the concept that all cations move via Sr vacancies.
Cation diffusion is several orders of magnitude slower than
oxygen diffusion.},
keywords = {J (WoSType)},
cin = {IFF-IEM / CNI},
ddc = {540},
cid = {I:(DE-Juel1)VDB321 / I:(DE-Juel1)VDB381},
pnm = {Materialien, Prozesse und Bauelemente für die Mikro- und
Nanoelektronik},
pid = {G:(DE-Juel1)FUEK252},
shelfmark = {Chemistry, Physical / Physics, Atomic, Molecular $\&$
Chemical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000228634500023},
doi = {10.1039/b418824a},
url = {https://juser.fz-juelich.de/record/46286},
}