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000046550 084__ $$2WoS$$aChemistry, Physical
000046550 1001_ $$0P:(DE-HGF)0$$aBóta, A.$$b0
000046550 245__ $$aEffects of contaminants on biological model membranes: The advantage of the ASAXS method for the study of the location of copper ions and dihalogenated phenol molecules
000046550 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2005
000046550 300__ $$a124 - 130
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000046550 440_0 $$01360$$aColloids and Surfaces A:Physicochemical and Engineering Aspects$$v265$$x0927-7757
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000046550 520__ $$aThe features of the location of copper ions and the dihalogenated phenol molecules were investigated at their low concentration in the dipalmitoylphosphatidylcholine (DPPC)-water liposomes by using small-angle X-ray scattering (SAXS) and anomalous small-angle X-ray scattering (ASAXS) methods. Only the ASAXS method can provide information about the structural features of the domains rich in these ions and organic guest molecules. The copper ions are mainly located in large domains between the lamellae and only partly in the characteristic periodic water shells of the liposomes. The dihalogenated phenol molecules are embedded in the layers and do not destroy the lamellar arrangement. Their inhomogeneous distribution appears laterally and phase separation occurs. The local structures induced by the copper ions and the dihalogenated phenols were also visualised by freeze-fracture method. (c) 2005 Elsevier B.V. All rights reserved.
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000046550 65320 $$2Author$$aanomalous small-angle X-ray scattering (ASAXS)
000046550 65320 $$2Author$$aliposome
000046550 65320 $$2Author$$alocalisation
000046550 65320 $$2Author$$aphase separation
000046550 65320 $$2Author$$aCopper(II) ion
000046550 65320 $$2Author$$adihalogenated phenol
000046550 7001_ $$0P:(DE-Juel1)129484$$aKlumpp, E.$$b1$$uFZJ
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000046550 8567_ $$uhttp://dx.doi.org/10.1016/j.colsurfa.2005.02.041
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