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@ARTICLE{Plieth:46693,
      author       = {Plieth, W. and Lorenz, W. J. and Staikov, G.},
      title        = {{B}ond {E}nergies in {A}lloys {D}etermined from
                      {U}nderpotential {D}eposition {P}otentials},
      journal      = {Journal of solid state electrochemistry},
      volume       = {8},
      issn         = {1432-8488},
      address      = {Berlin},
      publisher    = {Springer},
      reportid     = {PreJuSER-46693},
      pages        = {941 - 946},
      year         = {2004},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {A procedure is presented to determine bond energies between
                      the metal (Me) and substrate (S) components of binary alloys
                      from characteristic underpotential deposition (UPD)
                      potentials. The bond energy between Me and S atoms is one of
                      the factors governing the deposition kinetics and structure
                      of Me-S alloy deposits. The proposed procedure is based on
                      the determination of the UPD potential for formation of a
                      condensed two-dimensional (2D) phase of the less noble metal
                      Me (the UPD metal) on the more noble metal S (the
                      substrate). Making reasonable approximations, the
                      sublimation enthalpy of the condensed 2D Me phase is
                      obtained from the corresponding formation underpotential.
                      From this sublimation enthalpy the bond energy of an atom of
                      the UPD metal in a kink site position of the 2D Me phase is
                      calculated. This value is used to calculate the bond energy
                      (phi(Me-S)) between an Me atom and an S atom. The method is
                      demonstrated using experimental data obtained in selected
                      electrochemical UPD systems.},
      keywords     = {J (WoSType)},
      cin          = {ISG-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB43},
      pnm          = {Kondensierte Materie},
      pid          = {G:(DE-Juel1)FUEK242},
      shelfmark    = {Electrochemistry},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000224836000002},
      doi          = {10.1007/s10008-004-0513-1},
      url          = {https://juser.fz-juelich.de/record/46693},
}