Home > Workflow collections > Public records > Organic nitrate and secondary organic aerosol yield from NO3 oxidation of ß-pinene evaluated using a gas-phase kinetics/aerosol partitioning model > print

001     4703
005     20240712101004.0
024 7 _ |a WOS:000263642000024
|2 WOS
024 7 _ |a 2128/10167
|2 Handle
037 _ _ |a PreJuSER-4703
041 _ _ |a eng
082 _ _ |a 550
084 _ _ |2 WoS
|a Meteorology & Atmospheric Sciences
100 1 _ |0 P:(DE-HGF)0
|a Fry, J.L.
|b 0
245 _ _ |a Organic nitrate and secondary organic aerosol yield from NO3 oxidation of ß-pinene evaluated using a gas-phase kinetics/aerosol partitioning model
260 _ _ |a Katlenburg-Lindau
|b EGU
|c 2009
300 _ _ |a 1431 - 1449
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|0 0
|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |0 9601
|a Atmospheric Chemistry and Physics
|v 9
|x 1680-7316
500 _ _ |a The Berkeley authors were supported by NSF ATM-0639847 and NSF ATM-0511829. The authors thank Luke Valin for assistance running WRF/Chem; Klaus Scott for providing California monoterpene emissions estimates; Steve Ball and Bill Simpson for helpful comments on the manuscript; and the entire SAPHIR NO3 intercomparison campaign team, June 2007 at Forschungszentrum Julich, for their support of these experiments. This work was a joint activity of the European Network of Excellence ACCENT ( contract no: GOCE CT-2004-505337) and EUROCHAMP.
520 _ _ |a The yields of organic nitrates and of secondary organic aerosol (SOA) particle formation were measured for the reaction NO3+beta-pinene under dry and humid conditions in the atmosphere simulation chamber SAPHIR at Research Center Julich. These experiments were conducted at low concentrations of NO3 (NO3+N2O5 < 10 ppb) and beta-pinene (peak similar to 15 ppb), with no seed aerosol. SOA formation was observed to be prompt and substantial (similar to 50% mass yield under both dry conditions and at 60% RH), and highly correlated with organic nitrate formation. The observed gas/aerosol partitioning of organic nitrates can be simulated using an absorptive partitioning model to derive an estimated vapor pressure of the condensing nitrate species of p(vap) similar to 5x10(-6) Torr (6.67x10(-4) Pa), which constrains speculation about the oxidation mechanism and chemical identity of the organic nitrate. Once formed the SOA in this system continues to evolve, resulting in measurable aerosol volume decrease with time. The observations of high aerosol yield from NOx-dependent oxidation of monoterpenes provide an example of a significant anthropogenic source of SOA from biogenic hydrocarbon precursors. Estimates of the NO3+beta-pinene SOA source strength for California and the globe indicate that NO3 reactions with monoterpenes are likely an important source (0.5-8% of the global total) of organic aerosol on regional and global scales.
536 _ _ |0 G:(DE-Juel1)FUEK406
|2 G:(DE-HGF)
|a Atmosphäre und Klima
|c P22
|x 0
588 _ _ |a Dataset connected to Web of Science
650 _ 7 |2 WoSType
|a J
700 1 _ |0 P:(DE-Juel1)4528
|a Kiendler-Scharr, A.
|b 1
|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Rollins, A.W.
|b 2
700 1 _ |0 P:(DE-HGF)0
|a Wooldridge, P.J.
|b 3
700 1 _ |0 P:(DE-HGF)0
|a Brown, S.S.
|b 4
700 1 _ |0 P:(DE-Juel1)7363
|a Fuchs, H.
|b 5
|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Dube, W.
|b 6
700 1 _ |0 P:(DE-Juel1)VDB66036
|a Mensah, A.
|b 7
|u FZJ
700 1 _ |0 P:(DE-Juel1)VDB46017
|a Dal Maso, M.
|b 8
|u FZJ
700 1 _ |0 P:(DE-Juel1)5344
|a Tillmann, R.
|b 9
|u FZJ
700 1 _ |0 P:(DE-Juel1)16317
|a Dorn, H.-P.
|b 10
|u FZJ
700 1 _ |0 P:(DE-Juel1)16306
|a Brauers, T.
|b 11
|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Cohen, R.C.
|b 12
773 _ _ |0 PERI:(DE-600)2069847-1
|g Vol. 9, p. 1431 - 1449
|p 1431 - 1449
|q 9<1431 - 1449
|t Atmospheric chemistry and physics
|v 9
|x 1680-7316
|y 2009
856 4 _ |u https://juser.fz-juelich.de/record/4703/files/acp-9-1431-2009.pdf
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/4703/files/acp-9-1431-2009.gif?subformat=icon
|x icon
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/4703/files/acp-9-1431-2009.jpg?subformat=icon-180
|x icon-180
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/4703/files/acp-9-1431-2009.jpg?subformat=icon-700
|x icon-700
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/4703/files/acp-9-1431-2009.pdf?subformat=pdfa
|x pdfa
|y OpenAccess
909 C O |o oai:juser.fz-juelich.de:4703
|p openaire
|p open_access
|p driver
|p VDB
|p dnbdelivery
913 1 _ |0 G:(DE-Juel1)FUEK406
|a DE-HGF
|b Umwelt
|k P22
|l Atmosphäre und Klima
|v Atmosphäre und Klima
|x 0
|z fortgesetzt als P23
914 1 _ |y 2009
915 _ _ |a Creative Commons Attribution CC BY 3.0
|0 LIC:(DE-HGF)CCBY3
|2 HGFVOC
915 _ _ |a OpenAccess
|0 StatID:(DE-HGF)0510
|2 StatID
915 _ _ |a JCR/ISI refereed
|0 StatID:(DE-HGF)0010
920 1 _ |0 I:(DE-Juel1)VDB791
|d 30.09.2010
|g ICG
|k ICG-2
|l Troposphäre
|x 1
970 _ _ |a VDB:(DE-Juel1)111892
980 1 _ |a UNRESTRICTED
980 1 _ |a FullTexts
980 _ _ |a VDB
980 _ _ |a ConvertedRecord
980 _ _ |a journal
980 _ _ |a I:(DE-Juel1)IEK-8-20101013
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)ICE-3-20101013
981 _ _ |a I:(DE-Juel1)IEK-8-20101013

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21