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000004706 084__ $$2WoS$$aChemistry, Physical
000004706 084__ $$2WoS$$aPhysics, Atomic, Molecular & Chemical
000004706 1001_ $$0P:(DE-Juel1)5344$$aTillmann, R.$$b0$$uFZJ
000004706 245__ $$aTemperature dependence of the rate coefficient for the a-pinene reaction with ozone in the range between 243 K and 303 K
000004706 260__ $$aCambridge$$bRSC Publ.$$c2009
000004706 300__ $$a2323 - 2328
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000004706 440_0 $$04916$$aPhysical Chemistry Chemical Physics$$v11$$x1463-9076
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000004706 520__ $$aThe absolute rate coefficient for the reaction of alpha-pinene with ozone was determined in the temperature range between 243 K and 303 K at atmospheric pressure. In total, 30 experiments were performed in the large (85 m3) temperature-controlled simulation chamber AIDA, where the concentrations of the reactants ozone and alpha-pinene were measured directly. An Arrhenius expression for the alpha-pinene + ozone reaction was derived with a pre-exponential factor of (1.4 +/- 0.4) x 10(-15) cm3 s(-1) and a temperature coefficient of (833 +/- 86) K. This rate coefficient is in good agreement (-5%) with the current IUPAC (IUPAC 2007) recommendation at 298 K. The IUPAC recommendation is significantly larger (+27%), around 243 K where the recommended values were extrapolated from higher temperatures. This finding is relevant for tropical regions where strong updrafts can rapidly transport reactive hydrocarbons like alpha-pinene from the boundary layer into the cold regions of the free troposphere.
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000004706 650_2 $$2MeSH$$aAbsorption
000004706 650_2 $$2MeSH$$aKinetics
000004706 650_2 $$2MeSH$$aMass Spectrometry
000004706 650_2 $$2MeSH$$aMonoterpenes: chemistry
000004706 650_2 $$2MeSH$$aOzone: chemistry
000004706 650_2 $$2MeSH$$aProtons
000004706 650_2 $$2MeSH$$aTemperature
000004706 650_2 $$2MeSH$$aTropical Climate
000004706 650_2 $$2MeSH$$aUltraviolet Rays
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000004706 650_7 $$010028-15-6$$2NLM Chemicals$$aOzone
000004706 650_7 $$080-56-8$$2NLM Chemicals$$aalpha-pinene
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000004706 7001_ $$0P:(DE-HGF)0$$aSaathoff, H.$$b1
000004706 7001_ $$0P:(DE-Juel1)16306$$aBrauers, T.$$b2$$uFZJ
000004706 7001_ $$0P:(DE-Juel1)4528$$aKiendler-Scharr, A.$$b3$$uFZJ
000004706 7001_ $$0P:(DE-Juel1)16346$$aMentel, T. F.$$b4$$uFZJ
000004706 773__ $$0PERI:(DE-600)1476244-4$$a10.1039/b813407c$$gVol. 11, p. 2323 - 2328$$p2323 - 2328$$q11<2323 - 2328$$tPhysical Chemistry Chemical Physics$$v11$$x1463-9076$$y2009
000004706 8567_ $$uhttp://dx.doi.org/10.1039/b813407c
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