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@ARTICLE{Tillmann:4706,
      author       = {Tillmann, R. and Saathoff, H. and Brauers, T. and
                      Kiendler-Scharr, A. and Mentel, T. F.},
      title        = {{T}emperature dependence of the rate coefficient for the
                      a-pinene reaction with ozone in the range between 243 {K}
                      and 303 {K}},
      journal      = {Physical Chemistry Chemical Physics},
      volume       = {11},
      issn         = {1463-9076},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {PreJuSER-4706},
      pages        = {2323 - 2328},
      year         = {2009},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The absolute rate coefficient for the reaction of
                      alpha-pinene with ozone was determined in the temperature
                      range between 243 K and 303 K at atmospheric pressure. In
                      total, 30 experiments were performed in the large (85 m3)
                      temperature-controlled simulation chamber AIDA, where the
                      concentrations of the reactants ozone and alpha-pinene were
                      measured directly. An Arrhenius expression for the
                      alpha-pinene + ozone reaction was derived with a
                      pre-exponential factor of (1.4 +/- 0.4) x 10(-15) cm3 s(-1)
                      and a temperature coefficient of (833 +/- 86) K. This rate
                      coefficient is in good agreement $(-5\%)$ with the current
                      IUPAC (IUPAC 2007) recommendation at 298 K. The IUPAC
                      recommendation is significantly larger $(+27\%),$ around 243
                      K where the recommended values were extrapolated from higher
                      temperatures. This finding is relevant for tropical regions
                      where strong updrafts can rapidly transport reactive
                      hydrocarbons like alpha-pinene from the boundary layer into
                      the cold regions of the free troposphere.},
      keywords     = {Absorption / Kinetics / Mass Spectrometry / Monoterpenes:
                      chemistry / Ozone: chemistry / Protons / Temperature /
                      Tropical Climate / Ultraviolet Rays / Monoterpenes (NLM
                      Chemicals) / Protons (NLM Chemicals) / Ozone (NLM Chemicals)
                      / alpha-pinene (NLM Chemicals) / J (WoSType)},
      cin          = {ICG-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB791},
      pnm          = {Atmosphäre und Klima},
      pid          = {G:(DE-Juel1)FUEK406},
      shelfmark    = {Chemistry, Physical / Physics, Atomic, Molecular $\&$
                      Chemical},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:19305907},
      UT           = {WOS:000264374700022},
      doi          = {10.1039/b813407c},
      url          = {https://juser.fz-juelich.de/record/4706},
}