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@ARTICLE{Tillmann:4706,
author = {Tillmann, R. and Saathoff, H. and Brauers, T. and
Kiendler-Scharr, A. and Mentel, T. F.},
title = {{T}emperature dependence of the rate coefficient for the
a-pinene reaction with ozone in the range between 243 {K}
and 303 {K}},
journal = {Physical Chemistry Chemical Physics},
volume = {11},
issn = {1463-9076},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {PreJuSER-4706},
pages = {2323 - 2328},
year = {2009},
note = {Record converted from VDB: 12.11.2012},
abstract = {The absolute rate coefficient for the reaction of
alpha-pinene with ozone was determined in the temperature
range between 243 K and 303 K at atmospheric pressure. In
total, 30 experiments were performed in the large (85 m3)
temperature-controlled simulation chamber AIDA, where the
concentrations of the reactants ozone and alpha-pinene were
measured directly. An Arrhenius expression for the
alpha-pinene + ozone reaction was derived with a
pre-exponential factor of (1.4 +/- 0.4) x 10(-15) cm3 s(-1)
and a temperature coefficient of (833 +/- 86) K. This rate
coefficient is in good agreement $(-5\%)$ with the current
IUPAC (IUPAC 2007) recommendation at 298 K. The IUPAC
recommendation is significantly larger $(+27\%),$ around 243
K where the recommended values were extrapolated from higher
temperatures. This finding is relevant for tropical regions
where strong updrafts can rapidly transport reactive
hydrocarbons like alpha-pinene from the boundary layer into
the cold regions of the free troposphere.},
keywords = {Absorption / Kinetics / Mass Spectrometry / Monoterpenes:
chemistry / Ozone: chemistry / Protons / Temperature /
Tropical Climate / Ultraviolet Rays / Monoterpenes (NLM
Chemicals) / Protons (NLM Chemicals) / Ozone (NLM Chemicals)
/ alpha-pinene (NLM Chemicals) / J (WoSType)},
cin = {ICG-2},
ddc = {540},
cid = {I:(DE-Juel1)VDB791},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK406},
shelfmark = {Chemistry, Physical / Physics, Atomic, Molecular $\&$
Chemical},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:19305907},
UT = {WOS:000264374700022},
doi = {10.1039/b813407c},
url = {https://juser.fz-juelich.de/record/4706},
}