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| Home > Publications database > Temperature dependence of the rate coefficient for the a-pinene reaction with ozone in the range between 243 K and 303 K > print |
| 001 | 4706 | ||
| 005 | 20240709081732.0 | ||
| 024 | 7 | _ | |2 pmid |a pmid:19305907 |
| 024 | 7 | _ | |2 DOI |a 10.1039/b813407c |
| 024 | 7 | _ | |2 WOS |a WOS:000264374700022 |
| 024 | 7 | _ | |2 ISSN |a 1463-9076 |
| 037 | _ | _ | |a PreJuSER-4706 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 540 |
| 084 | _ | _ | |2 WoS |a Chemistry, Physical |
| 084 | _ | _ | |2 WoS |a Physics, Atomic, Molecular & Chemical |
| 100 | 1 | _ | |a Tillmann, R. |b 0 |u FZJ |0 P:(DE-Juel1)5344 |
| 245 | _ | _ | |a Temperature dependence of the rate coefficient for the a-pinene reaction with ozone in the range between 243 K and 303 K |
| 260 | _ | _ | |c 2009 |a Cambridge |b RSC Publ. |
| 300 | _ | _ | |a 2323 - 2328 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |a Physical Chemistry Chemical Physics |x 1463-9076 |0 4916 |v 11 |
| 500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
| 520 | _ | _ | |a The absolute rate coefficient for the reaction of alpha-pinene with ozone was determined in the temperature range between 243 K and 303 K at atmospheric pressure. In total, 30 experiments were performed in the large (85 m3) temperature-controlled simulation chamber AIDA, where the concentrations of the reactants ozone and alpha-pinene were measured directly. An Arrhenius expression for the alpha-pinene + ozone reaction was derived with a pre-exponential factor of (1.4 +/- 0.4) x 10(-15) cm3 s(-1) and a temperature coefficient of (833 +/- 86) K. This rate coefficient is in good agreement (-5%) with the current IUPAC (IUPAC 2007) recommendation at 298 K. The IUPAC recommendation is significantly larger (+27%), around 243 K where the recommended values were extrapolated from higher temperatures. This finding is relevant for tropical regions where strong updrafts can rapidly transport reactive hydrocarbons like alpha-pinene from the boundary layer into the cold regions of the free troposphere. |
| 536 | _ | _ | |a Atmosphäre und Klima |c P22 |2 G:(DE-HGF) |0 G:(DE-Juel1)FUEK406 |x 0 |
| 588 | _ | _ | |a Dataset connected to Web of Science, Pubmed |
| 650 | _ | 2 | |2 MeSH |a Absorption |
| 650 | _ | 2 | |2 MeSH |a Kinetics |
| 650 | _ | 2 | |2 MeSH |a Mass Spectrometry |
| 650 | _ | 2 | |2 MeSH |a Monoterpenes: chemistry |
| 650 | _ | 2 | |2 MeSH |a Ozone: chemistry |
| 650 | _ | 2 | |2 MeSH |a Protons |
| 650 | _ | 2 | |2 MeSH |a Temperature |
| 650 | _ | 2 | |2 MeSH |a Tropical Climate |
| 650 | _ | 2 | |2 MeSH |a Ultraviolet Rays |
| 650 | _ | 7 | |0 0 |2 NLM Chemicals |a Monoterpenes |
| 650 | _ | 7 | |0 0 |2 NLM Chemicals |a Protons |
| 650 | _ | 7 | |0 10028-15-6 |2 NLM Chemicals |a Ozone |
| 650 | _ | 7 | |0 80-56-8 |2 NLM Chemicals |a alpha-pinene |
| 650 | _ | 7 | |a J |2 WoSType |
| 700 | 1 | _ | |a Saathoff, H. |b 1 |0 P:(DE-HGF)0 |
| 700 | 1 | _ | |a Brauers, T. |b 2 |u FZJ |0 P:(DE-Juel1)16306 |
| 700 | 1 | _ | |a Kiendler-Scharr, A. |b 3 |u FZJ |0 P:(DE-Juel1)4528 |
| 700 | 1 | _ | |a Mentel, T. F. |b 4 |u FZJ |0 P:(DE-Juel1)16346 |
| 773 | _ | _ | |0 PERI:(DE-600)1476244-4 |a 10.1039/b813407c |g Vol. 11, p. 2323 - 2328 |p 2323 - 2328 |q 11<2323 - 2328 |t Physical Chemistry Chemical Physics |v 11 |x 1463-9076 |y 2009 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1039/b813407c |
| 909 | C | O | |o oai:juser.fz-juelich.de:4706 |p VDB |
| 913 | 1 | _ | |k P22 |v Atmosphäre und Klima |l Atmosphäre und Klima |b Umwelt |z fortgesetzt als P23 |0 G:(DE-Juel1)FUEK406 |x 0 |
| 914 | 1 | _ | |y 2009 |
| 915 | _ | _ | |a JCR/ISI refereed |0 StatID:(DE-HGF)0010 |2 StatID |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 920 | 1 | _ | |k ICG-2 |l Troposphäre |d 30.09.2010 |g ICG |0 I:(DE-Juel1)VDB791 |x 1 |
| 970 | _ | _ | |a VDB:(DE-Juel1)111895 |
| 980 | _ | _ | |a VDB |
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| 980 | _ | _ | |a journal |
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| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)ICE-3-20101013 |
| 981 | _ | _ | |a I:(DE-Juel1)IEK-8-20101013 |
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