TY - JOUR AU - do Monte, S. A. AU - Müller, T. AU - Dallos, M. AU - Lischka, H. AU - Diedenhofen, M. AU - Klamt, A. TI - Solvent effects in electronically excited states using the continuum solvation model COSMO in combination with multireference configuration interaction with single and doubles (MR-CISD) JO - Theoretical chemistry accounts VL - 111 SN - 1432-881X CY - Berlin PB - Springer M1 - PreJuSER-47321 PY - 2004 N1 - Record converted from VDB: 12.11.2012 AB - An implementation of the COSMO continuum solvation model into the MCSCF and MR-CISD programs of the COLUMBUS program system is reported. Equilibrium solvation and non-equilibrium solvation models for the treatment of electronic excitations have been used. Solvatochromic effects have been computed for a representative set of n-pi* and pi-pi* states of formaldehyde, acrolein and pyrazine using several solvents ranging from some with apolar character to water. Agreement with experimental shifts is good within the limits of a continuum model. KW - J (WoSType) LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000220424700005 DO - DOI:10.1007/s00214-003-0530-7 UR - https://juser.fz-juelich.de/record/47321 ER -