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@ARTICLE{Watanabe:47322,
author = {Watanabe, N. and Kamata, Y. and Yamauchi, K. and Udagawa,
Y. and Müller, T.},
title = {{C}oulomb hole in {N}2, {CO} and {O}2 deduced from {X}-ray
scattering cross-sections},
journal = {Molecular physics},
volume = {102},
issn = {0026-8976},
address = {London},
publisher = {Taylor $\&$ Francis},
reportid = {PreJuSER-47322},
pages = {649 - 657},
year = {2004},
note = {Record converted from VDB: 12.11.2012},
abstract = {Accurate total ( elastic and inelastic) X-ray scattering
cross-sections sigma(ee)(q) of N-2, CO and O-2 were measured
by the use of the energy dispersive method up to a momentum
transfer of q = 12 au. The radial electron pair distribution
function P(r(12)) was extracted from the cross-sections. The
Coulomb hole, defined as the difference between the exact
P(r(12)) and the corresponding function evaluated at the
Hartree-Fock limit, has been derived from experimental data
for the first time. Comparison of multi-reference
configuration interaction (MRCI) and averaged quadratic
coupled cluster (MR-AQCC) calculations indicates substantial
shortcomings of MRCI due to the lack of size extensivity.
The overall agreement with experiment is good but some
differences between the theoretical and experimental results
remain.},
keywords = {J (WoSType)},
cin = {ZAM},
ddc = {530},
cid = {I:(DE-Juel1)VDB62},
pnm = {Betrieb und Weiterentwicklung des Höchstleistungsrechners},
pid = {G:(DE-Juel1)FUEK254},
shelfmark = {Physics, Atomic, Molecular $\&$ Chemical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000221801400003},
doi = {10.1080/0026897041001695697},
url = {https://juser.fz-juelich.de/record/47322},
}