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000047354 084__ $$2WoS$$aChemistry, Physical
000047354 084__ $$2WoS$$aPhysics, Condensed Matter
000047354 1001_ $$0P:(DE-Juel1)VDB3067$$aSchober, T.$$b0$$uFZJ
000047354 245__ $$aTransformation of an oxygen ion conductor to a proton conductor by solid state reaction
000047354 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2005
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000047354 440_0 $$05565$$aSolid State Ionics$$v176$$x0167-2738$$y29
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000047354 520__ $$aIt is shown that starting from a thin, gas tight layer of an oxygen ion conductor such as 8YSZ a thin, gas tight layer of a proton conductor can be obtained by coating the original layer with BaCO3 or BaO followed by sintering. Generally, a homogeneous Zr1-xYxO2-y ceramic compound will react with BaO to form the desired proton conductor BaZr1-xYxO3. sThis procedure obviates the deposition of proton conducting layers starting from fine powders which in view of the poor sinterabilty of the common proton conductors was a difficult endeavor in the past. It also permits the construction of larger components (reactors etc.) covered with a proton conductor. The present technique is also applicable to the formation of CZI10 (CaZr0.9In0.1O3-y) layers. The latter compound is an excellent proton conductor for potentiometric purposes and has seen commercial use in hydrogen sensors in molten aluminium (5). (c) 2005 Elsevier B.V. All rights reserved.
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000047354 65320 $$2Author$$aoxygen ion conduction
000047354 65320 $$2Author$$aproton conduction
000047354 65320 $$2Author$$afuel cell
000047354 65320 $$2Author$$athin film
000047354 65320 $$2Author$$asensors
000047354 773__ $$0PERI:(DE-600)1500750-9$$a10.1016/j.ssi.2005.06.021$$gVol. 176$$q176$$tSolid state ionics$$v176$$x0167-2738$$y2005
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