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@ARTICLE{Schober:47354,
author = {Schober, T.},
title = {{T}ransformation of an oxygen ion conductor to a proton
conductor by solid state reaction},
journal = {Solid state ionics},
volume = {176},
issn = {0167-2738},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PreJuSER-47354},
year = {2005},
note = {Record converted from VDB: 12.11.2012},
abstract = {It is shown that starting from a thin, gas tight layer of
an oxygen ion conductor such as 8YSZ a thin, gas tight layer
of a proton conductor can be obtained by coating the
original layer with BaCO3 or BaO followed by sintering.
Generally, a homogeneous Zr1-xYxO2-y ceramic compound will
react with BaO to form the desired proton conductor
BaZr1-xYxO3. sThis procedure obviates the deposition of
proton conducting layers starting from fine powders which in
view of the poor sinterabilty of the common proton
conductors was a difficult endeavor in the past. It also
permits the construction of larger components (reactors
etc.) covered with a proton conductor. The present technique
is also applicable to the formation of CZI10
(CaZr0.9In0.1O3-y) layers. The latter compound is an
excellent proton conductor for potentiometric purposes and
has seen commercial use in hydrogen sensors in molten
aluminium (5). (c) 2005 Elsevier B.V. All rights reserved.},
keywords = {J (WoSType)},
cin = {IFF-IEM},
ddc = {530},
cid = {I:(DE-Juel1)VDB321},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK242},
shelfmark = {Chemistry, Physical / Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000232289500013},
doi = {10.1016/j.ssi.2005.06.021},
url = {https://juser.fz-juelich.de/record/47354},
}