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@ARTICLE{Plenge:47475,
      author       = {Plenge, J. and Kühl, S. and Vogel, B. and Müller, R. and
                      Stroh, F. and von Hobe, M. and Flesch, R. and Rühl, E.},
      title        = {{B}ond strength of chlorine peroxide},
      journal      = {The journal of physical chemistry / A},
      volume       = {109},
      issn         = {1089-5639},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {PreJuSER-47475},
      pages        = {6730 - 6734},
      year         = {2005},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The bond strength of chlorine peroxide (ClOOCl) is studied
                      by photoionization mass spectrometry. The experimental
                      results are obtained from the fragmentation threshold
                      yielding ClO+, which is observed at 11.52 +/- 0.025 eV. The
                      O-O bond strength D(o) is derived from this value in
                      comparison to the first ionization energy of ClO, yielding
                      D(o)298 = 72.39 +/- 2.8 kJ mol(-1). The present work
                      provides a new and independent method to examine the
                      equilibrium constant K(eq) for chlorine peroxide formation
                      via dimerization of ClO in the stratosphere. This yields an
                      approximation for the equilibrium constant in the
                      stratospheric temperature regime between 190 and 230 K of
                      the form K(eq) = 1.92 x 10(-27) cm3 molecules(-1) x exp(8430
                      K/T). This value of K(eq) is lower than current reference
                      data and agrees well with high altitude aircraft
                      measurements within their scattering range. Considering the
                      error limits of the present experimental results and the
                      resulting equilibrium constant, there is agreement with
                      previous works, but the upper limit of current reference
                      values appears to be too high. This result is discussed
                      along with possible atmospheric implications.},
      keywords     = {J (WoSType)},
      cin          = {ICG-I},
      ddc          = {530},
      cid          = {I:(DE-Juel1)VDB47},
      pnm          = {Chemie und Dynamik der Geo-Biosphäre},
      pid          = {G:(DE-Juel1)FUEK257},
      shelfmark    = {Chemistry, Physical / Physics, Atomic, Molecular $\&$
                      Chemical},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:16834026},
      UT           = {WOS:000230897000015},
      doi          = {10.1021/jp044142h},
      url          = {https://juser.fz-juelich.de/record/47475},
}