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@ARTICLE{Marienhagen:47527,
author = {Marienhagen, J. and Kennerknecht, N. and Sahm, H. and
Eggeling, L.},
title = {{F}unctional analysis of all aminotransferase proteins
inferred from the genome sequence of {C}orynebacterium
glutamicum},
journal = {Journal of bacteriology},
volume = {187},
issn = {0021-9193},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PreJuSER-47527},
pages = {7639 - 7646},
year = {2005},
note = {Record converted from VDB: 12.11.2012},
abstract = {Twenty putative aminotransferase (AT) proteins of
Corynebacterium glutamicum, or rather pyridoxal-5'-phosphate
(PLP)-dependent enzymes, were isolated and assayed among
others with L-glutamate, L-aspartate, and L-alanine as amino
donors and a number of 2-oxo-acids as amino acceptors. One
outstanding AT identified is AlaT, which has a broad amino
donor specificity utilizing (in the order of preference)
L-glutamate > 2-aminobutyrate > L-aspartate with pyruvate as
acceptor. Another AT is AvtA, which utilizes L-alanine to
aminate 2-oxo-isovalerate, the L-valine precursor, and
2-oxo-butyrate. A second AT active with the L-valine
precursor and that of the other two branched-chain amino
acids, too, is IlvE, and both enzyme activities overlap
partially in vivo, as demonstrated by the analysis of
deletion mutants. Also identified was AroT, the aromatic AT,
and this and IlvE were shown to have comparable activities
with phenylpyruvate, thus demonstrating the relevance of
both ATs for L-phenylalanine synthesis. We also assessed the
activity of two PLP-containing cysteine desulfurases,
supplying a persulfide intermediate. One of them is SufS,
which assists in the sulfur transfer pathway for the Fe-S
cluster assembly. Together with the identification of
further ATs and the additional analysis of deletion mutants,
this results in an overview of the ATs within an organism
that may not have been achieved thus far.},
keywords = {Alanine: metabolism / Aspartic Acid: metabolism / Bacterial
Proteins: genetics / Bacterial Proteins: isolation $\&$
purification / Bacterial Proteins: metabolism / Butyric
Acids: metabolism / Carbon-Sulfur Lyases: metabolism /
Corynebacterium glutamicum: enzymology / Corynebacterium
glutamicum: genetics / Gene Deletion / Glutamic Acid:
metabolism / Keto Acids: metabolism / Phenylpyruvic Acids:
metabolism / Pyruvic Acid: metabolism / Substrate
Specificity / Transaminases: genetics / Transaminases:
isolation $\&$ purification / Transaminases: metabolism /
Bacterial Proteins (NLM Chemicals) / Butyric Acids (NLM
Chemicals) / Keto Acids (NLM Chemicals) / Phenylpyruvic
Acids (NLM Chemicals) / Pyruvic Acid (NLM Chemicals) /
alpha-keto-beta-methylvaleric acid (NLM Chemicals) /
phenylpyruvic acid (NLM Chemicals) / Alanine (NLM Chemicals)
/ Aspartic Acid (NLM Chemicals) / Glutamic Acid (NLM
Chemicals) / alpha-ketobutyric acid (NLM Chemicals) /
alpha-ketoisovalerate (NLM Chemicals) / alpha-ketoisocaproic
acid (NLM Chemicals) / Transaminases (NLM Chemicals) /
Carbon-Sulfur Lyases (NLM Chemicals) / cysteine desulfurase
(NLM Chemicals) / J (WoSType)},
cin = {IBT-1},
ddc = {570},
cid = {I:(DE-Juel1)VDB55},
pnm = {Biotechnologie},
pid = {G:(DE-Juel1)FUEK256},
shelfmark = {Microbiology},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:16267288},
pmc = {pmc:PMC1280304},
UT = {WOS:000233400200011},
doi = {10.1128/JB.187.22.7639-7646.2005},
url = {https://juser.fz-juelich.de/record/47527},
}