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@ARTICLE{Kaufmann:47842,
      author       = {Kaufmann, M. and Gil-Lopez, S. and Lopez-Puertas, M. and
                      Funke, B. and Garcia-Comas, M. J. and Koukouli, M. E. and
                      Glatthor, G. P. and Grabowski, U. and Hoepfner, M. and
                      Stiller, G. P. and von Clarmann, T. and Hoffmann, L. and
                      Riese, M.},
      title        = {{V}ibrationally excited ozone in the middle atmosphere},
      journal      = {Journal of Atmospheric and Solar-Terrestrial Physics},
      volume       = {68},
      issn         = {1364-6826},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {PreJuSER-47842},
      pages        = {202 - 212},
      year         = {2006},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Daytime mesospheric limb emission spectra of ozone in the
                      4.8 mu m regime are analyzed with respect to vibrational
                      excitation and relaxation processes. The data, which was
                      obtained by the MIPAS (Michelson Interferometer for Passive
                      Atmospheric Sounding) instrument on board ESA's
                      Environmental Satellite, is simulated by means of a
                      non-local thermodynamic equilibrium (non-LTE) model
                      utilizing O-3-abundance, temperature, and pressure data from
                      simultaneous retrievals in other spectral regions. The
                      vibrational states of ozone depart from LTE due to the
                      absorption of radiation from the lower atmosphere and due to
                      the production of excited states in the O + O-2 + M ->
                      O-3(v) + M recombination reaction. The energy flow into the
                      ozone molecule as well as the collisional relaxation are
                      highly uncertain. Model calculations that assume Ozone
                      formation at energies larger than 5000 cm(-1) underestimate
                      the measured radiances by a factor of 2-3 in the 50-75 km
                      altitude regime, if the nominal relaxation scheme is
                      assumed. Agreement between measured and modeled radiances is
                      achieved, if the collisional rates for the transformation of
                      hot band stretching to bending quanta are reduced by about a
                      factor of three, or if the quasi-nascent distribution of
                      ozone favors vibrational states in the 3000 cm(-1) region.
                      (c) 2005 Elsevier Ltd. All rights reserved.},
      keywords     = {J (WoSType)},
      cin          = {ICG-I / JARA-SIM},
      ddc          = {530},
      cid          = {I:(DE-Juel1)VDB47 / I:(DE-Juel1)VDB1045},
      pnm          = {Atmosphäre und Klima},
      pid          = {G:(DE-Juel1)FUEK406},
      shelfmark    = {Geochemistry $\&$ Geophysics / Meteorology $\&$ Atmospheric
                      Sciences},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000234895700006},
      doi          = {10.1016/j.jastp.2005.10.006},
      url          = {https://juser.fz-juelich.de/record/47842},
}