% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Bejan:48758,
      author       = {Bejan, I. and Abd El Aal, Y. and Barnes, I. and Benter, T.
                      and Bohn, B. and Wiesen, P. and Kleffmann, J.},
      title        = {{T}he photolysis of ortho-nitrophenols: {A} new gas phase
                      source of {HONO}},
      journal      = {Physical Chemistry Chemical Physics},
      volume       = {8},
      issn         = {1463-9076},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {PreJuSER-48758},
      pages        = {2028 - 2035},
      year         = {2006},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Formation of nitrous acid (HONO) in the gas phase has been
                      observed for the first time in a flow tube photoreactor upon
                      irradiation (lambda = 300-500 nm) of 2-nitrophenol and
                      methyl substituted derivatives using a selective and
                      sensitive instrument (LOPAP) for the detection of HONO.
                      Formation of HONO by heterogeneous NO2 photochemistry has
                      been excluded, since production of NO2 under the
                      experimental conditions is negligible. Variation of the
                      surface to volume ratio and the nitrophenol concentration
                      showed that the photolysis occurred in the gas phase
                      indicating that HONO formation is initiated by
                      intramolecular hydrogen transfer from the phenolic OH group
                      to the nitro group. From the measured linear dependence of
                      the HONO formation rate on the reactant's concentration and
                      photolysis light intensity, a non-negligible new HONO source
                      is proposed for the urban atmosphere during the day.
                      Unexpectedly high HONO mixing ratios have been observed
                      recently in several field campaigns during the day. It is
                      proposed that the photolysis of aromatic compounds
                      containing the ortho-nitrophenol entity could help to
                      explain, at least in part, this high contribution of HONO to
                      the oxidation capacity of the urban atmosphere.},
      keywords     = {J (WoSType)},
      cin          = {ICG-II},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB48},
      pnm          = {Atmosphäre und Klima},
      pid          = {G:(DE-Juel1)FUEK406},
      shelfmark    = {Chemistry, Physical / Physics, Atomic, Molecular $\&$
                      Chemical},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:16633690},
      UT           = {WOS:000236970300006},
      doi          = {10.1039/b516590c},
      url          = {https://juser.fz-juelich.de/record/48758},
}