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@ARTICLE{Kuklin:49348,
author = {Kuklin, A. I. and Ozerin, A. N. and Islamov, A. Kh. and
Muzafarov, A. M. and Gordeliy, V. I. and Rebrov, E. and
Ignateva, G. M. and Ozerina, L. A. and Tatarinova, E. A. and
Mukhametzianov, R. I. and Ozerina, L. A. and Sharipov, E.
Yu.},
title = {{T}he spacial structure of dendritic macromolecules},
journal = {Journal of applied crystallography},
volume = {38},
issn = {0021-8898},
address = {Copenhagen},
publisher = {Munksgaard},
reportid = {PreJuSER-49348},
pages = {996 - 1003},
year = {2005},
note = {Record converted from VDB: 12.11.2012},
abstract = {A low-resolution ab initio shape determination was
performed from small-angle neutron and X-ray scattering
(SANS and SAXS) curves from solutions of polycarbosilane
dendrimers with the three-functional and the four-functional
branching centre of the fourth, fifth, sixth, seventh and
eighth generations. In all cases, anisometric dendrimer
shapes were obtained. The overall shapes of the dendrimers
with the three-and four-functional branching centres were
oblate ellipsoids of revolution and triaxial ellipsoids,
respectively. The restored bead models revealed a pronounced
heterogeneity within the dendrimer structure. The density
deficit was observed in the central part and close to the
periphery of the dendrimers. The fraction of the overall
volume of the dendrimers available for solvent penetration
was about 0.2-0.3. These results may help in the design of
new practical applications of dendrimer macromolecules.},
keywords = {J (WoSType)},
cin = {IBI-2},
ddc = {540},
cid = {I:(DE-Juel1)VDB58},
pnm = {Neurowissenschaften},
pid = {G:(DE-Juel1)FUEK255},
shelfmark = {Crystallography},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000233271100017},
doi = {10.1107/S0021889805032115},
url = {https://juser.fz-juelich.de/record/49348},
}