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@ARTICLE{Meyer:49700,
author = {Meyer, R. and Guo, X. and Waser, R.},
title = {{N}onlinear electrical properties of grain boundaries in
oxygen ion conductors - {M}odeling the varistor behavior},
journal = {Electrochemical and solid-state letters},
volume = {8},
issn = {1099-0062},
address = {Pennington, NJ},
publisher = {Soc.},
reportid = {PreJuSER-49700},
pages = {E67},
year = {2005},
note = {Record converted from VDB: 12.11.2012},
abstract = {We report on numerical simulations of the grain-boundary
varistor behavior recently observed in Y2O3-doped CeO2 of
high purity. The aim of this study is to disclose the nature
of the nonlinear electrical properties of the grain
boundaries in oxygen ion conductors. Under small voltages (<
25 mV), the simulation shows a linear current-voltage
relation dominated by the grain-boundary resistance. Under
intermediate voltages (25-200 mV), the simulation discloses
a grain-boundary resistance breakdown and a nonlinear
current-voltage relation. The increase of ionic charge
carriers in the grain-boundary space-charge layer is the
cause for the nonlinear behavior. Calculations are compared
to experimental results. (c) 2005 The Electrochemical
Society.},
keywords = {J (WoSType)},
cin = {IFF-IEM},
ddc = {540},
cid = {I:(DE-Juel1)VDB321},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK242},
shelfmark = {Electrochemistry / Materials Science, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000231390900030},
doi = {10.1149/1.2008940},
url = {https://juser.fz-juelich.de/record/49700},
}